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Theoretical modeling of iodine value and saponification value of biodiesel fuels from their fatty acid composition

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  • Gopinath, A.
  • Puhan, Sukumar
  • Nagarajan, G.

Abstract

Biodiesel is an alternative fuel consisting of alkyl esters of fatty acids from vegetable oils or animal fats. The properties of biodiesel depend on the type of vegetable oil used for the transesterification process. The objective of the present work is to theoretically predict the iodine value and the saponification value of different biodiesels from their fatty acid methyl ester composition. The fatty acid ester compositions and the above values of different biodiesels were taken from the available published data. A multiple linear regression model was developed to predict the iodine value and saponification value of different biodiesels. The predicted results showed that the prediction errors were less than 3.4% compared to the available published data. The predicted values were also verified by substituting in the available published model which was developed to predict the higher heating values of biodiesel fuels from their iodine value and the saponification value. The resulting heating values of biodiesels were then compared with the published heating values and reported.

Suggested Citation

  • Gopinath, A. & Puhan, Sukumar & Nagarajan, G., 2009. "Theoretical modeling of iodine value and saponification value of biodiesel fuels from their fatty acid composition," Renewable Energy, Elsevier, vol. 34(7), pages 1806-1811.
    • Handle: RePEc:eee:renene:v:34:y:2009:i:7:p:1806-1811
    DOI: 10.1016/j.renene.2008.11.023
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    Cited by:

    1. Wenbo Ai & Haeng Muk Cho, 2024. "Predictive Models for Biodiesel Performance and Emission Characteristics in Diesel Engines: A Review," Energies, MDPI, vol. 17(19), pages 1-25, September.
    2. Giakoumis, Evangelos G., 2013. "A statistical investigation of biodiesel physical and chemical properties, and their correlation with the degree of unsaturation," Renewable Energy, Elsevier, vol. 50(C), pages 858-878.
    3. Pekkoh, Jeeraporn & Ruangrit, Khomsan & Aurepatipan, Nathapat & Duangjana, Kritsana & Sensupa, Sritip & Pumas, Chayakorn & Chaichana, Chatchawan & Pathom-aree, Wasu & Kato, Yasuo & Srinuanpan, Sirasit, 2024. "CO2 to green fuel converter: Photoautotrophic-cultivation of microalgae and its lipids conversion to biodiesel," Renewable Energy, Elsevier, vol. 222(C).
    4. Kumar, Niraj & Varun, & Chauhan, Sant Ram, 2013. "Performance and emission characteristics of biodiesel from different origins: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 633-658.
    5. Hassan, Aso A. & Smith, Joseph D., 2020. "Investigation of microwave-assisted transesterification reactor of waste cooking oil," Renewable Energy, Elsevier, vol. 162(C), pages 1735-1746.
    6. Díez Valbuena, G. & García Tuero, A. & Díez, J. & Rodríguez, E. & Hernández Battez, A., 2024. "Application of machine learning techniques to predict biodiesel iodine value," Energy, Elsevier, vol. 292(C).
    7. Bukkarapu, Kiran Raj & Krishnasamy, Anand, 2022. "A critical review on available models to predict engine fuel properties of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 155(C).
    8. Wahyudi & I.N.G. Wardana & Agung Widodo & Widya Wijayanti, 2018. "Improving Vegetable Oil Properties by Transforming Fatty Acid Chain Length in Jatropha Oil and Coconut Oil Blends," Energies, MDPI, vol. 11(2), pages 1-12, February.
    9. Patel, Alok & Arora, Neha & Mehtani, Juhi & Pruthi, Vikas & Pruthi, Parul A., 2017. "Assessment of fuel properties on the basis of fatty acid profiles of oleaginous yeast for potential biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 604-616.
    10. Sajjadi, Baharak & Raman, Abdul Aziz Abdul & Arandiyan, Hamidreza, 2016. "A comprehensive review on properties of edible and non-edible vegetable oil-based biodiesel: Composition, specifications and prediction models," Renewable and Sustainable Energy Reviews, Elsevier, vol. 63(C), pages 62-92.
    11. Maneechote, Wageeporn & Cheirsilp, Benjamas & Liewtrakul, Naruepon & Srinuanpan, Sirasit & Pathom-aree, Wasu & Phusunti, Neeranuch, 2023. "Production of microalgal biomass and lipids with superior biodiesel-properties by manipulating various trophic modes and simultaneously optimizing key energy sources," Renewable Energy, Elsevier, vol. 202(C), pages 797-808.
    12. Giakoumis, Evangelos G., 2018. "Analysis of 22 vegetable oils’ physico-chemical properties and fatty acid composition on a statistical basis, and correlation with the degree of unsaturation," Renewable Energy, Elsevier, vol. 126(C), pages 403-419.
    13. Jain, Siddharth & Sharma, M.P., 2010. "Biodiesel production from Jatropha curcas oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(9), pages 3140-3147, December.
    14. Yaakob, Zahira & Narayanan, Binitha N. & Padikkaparambil, Silija & Unni K., Surya & Akbar P., Mohammed, 2014. "A review on the oxidation stability of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 35(C), pages 136-153.

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