IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v33y2008i2p193-196.html
   My bibliography  Save this article

Magnesium borohydride: A new hydrogen storage material

Author

Listed:
  • Matsunaga, T.
  • Buchter, F.
  • Miwa, K.
  • Towata, S.
  • Orimo, S.
  • Züttel, A.

Abstract

Magnesium borohydride (Mg(BH4)2) is a promising material for hydrogen storage because of its high gravimetric storage density (15.0mass%). We intended to synthesize Mg(BH4)2 by decomposition reaction of LiBH4 with MgCl2 by heat treatment without using a solvent, where the product consists of LiCl and a compound of magnesium, boron and hydrogen. Hydrogen desorption temperature of the product is approximately 100K lower than that of LiBH4 and the decomposition consists of a two-step reaction. The products of the 1st and 2nd decomposition reactions are MgH2 and Mg, respectively. This result indicates the following two-step reaction (1st reaction: Mg(BH4)2→MgH2+2B+3H2, 2nd reaction: MgH2→Mg+H2). The first decomposition peak is dominant and is around 563K. The 2nd decomposition occurs at the temperature greater than 590K.

Suggested Citation

  • Matsunaga, T. & Buchter, F. & Miwa, K. & Towata, S. & Orimo, S. & Züttel, A., 2008. "Magnesium borohydride: A new hydrogen storage material," Renewable Energy, Elsevier, vol. 33(2), pages 193-196.
  • Handle: RePEc:eee:renene:v:33:y:2008:i:2:p:193-196
    DOI: 10.1016/j.renene.2007.05.004
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148107001450
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.renene.2007.05.004?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Çakanyıldırım, Çetin & Gürü, Metin, 2009. "Production of NaBH4 and hydrogen release with catalyst," Renewable Energy, Elsevier, vol. 34(11), pages 2362-2365.
    2. Che Lah, Nurul Akmal, 2021. "Late transition metal nanocomplexes: Applications for renewable energy conversion and storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    3. Hai-Wen Li & Yigang Yan & Shin-ichi Orimo & Andreas Züttel & Craig M. Jensen, 2011. "Recent Progress in Metal Borohydrides for Hydrogen Storage," Energies, MDPI, vol. 4(1), pages 1-30, January.
    4. Komova, O.V. & Simagina, V.I. & Butenko, V.R. & Odegova, G.V. & Bulavchenko, O.A. & Nikolaeva, O.A. & Ozerova, A.M. & Lipatnikova, I.L. & Tayban, E.S. & Mukha, S.A. & Netskina, O.V., 2022. "Dehydrogenation of ammonia borane recrystallized by different techniques," Renewable Energy, Elsevier, vol. 184(C), pages 460-472.
    5. Zhang, Yanghuan & Zhang, Wei & Bu, Wengang & Cai, Ying & Qi, Yan & Guo, Shihai, 2019. "Improved hydrogen storage dynamics of amorphous and nanocrystalline Ce-Mg-Ni-based CeMg12-type alloys synthesized by ball milling," Renewable Energy, Elsevier, vol. 132(C), pages 167-175.
    6. Çakanyıldırım, Çetin & Gürü, Metin, 2008. "Processing of LiBH4 from its elements by ball milling method," Renewable Energy, Elsevier, vol. 33(11), pages 2388-2392.
    7. Cermak, Jiri & Kral, Lubomir & Roupcova, Pavla, 2022. "Hydrogen storage in TiVCrMo and TiZrNbHf multiprinciple-element alloys and their catalytic effect upon hydrogen storage in Mg," Renewable Energy, Elsevier, vol. 188(C), pages 411-424.
    8. Çakanyıldırım, Çetin & Gürü, Metin, 2010. "Supported CoCl2 catalyst for NaBH4 dehydrogenation," Renewable Energy, Elsevier, vol. 35(4), pages 839-844.
    9. Nathalie Sick & Matthias Blug & Jens Leker, 2014. "The Influence of Raw Material Prices on the Development of Hydrogen Storage Materials: The Case of Metal Hydrides," Journal of the Knowledge Economy, Springer;Portland International Center for Management of Engineering and Technology (PICMET), vol. 5(4), pages 735-760, December.
    10. Olena Zavorotynska & Stefano Deledda & Jenny G. Vitillo & Ivan Saldan & Matylda N. Guzik & Marcello Baricco & John C. Walmsley & Jiri Muller & Bjørn C. Hauback, 2015. "Combined X-ray and Raman Studies on the Effect of Cobalt Additives on the Decomposition of Magnesium Borohydride," Energies, MDPI, vol. 8(9), pages 1-18, August.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:33:y:2008:i:2:p:193-196. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.