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Selective hydrodeoxygenation of lignin model compound to renewable fuel precursors using two-dimensional nanosheet Ni/HZ5-NS catalyst

Author

Listed:
  • Lin, Feng
  • Ma, Yulong
  • Sun, Yonggang
  • Song, Zhi
  • Men, Xiuqin
  • Wu, Yuhua
  • Zhu, Yingbo
  • Gao, Tingting
  • Zhong, Yudan

Abstract

The catalytic upgrading of renewable lignin to value-added transportation fuels and chemicals is considered as the best solution to environmental and energy-related issues, however, such conversions are challenging. In this study, a new type of two-dimensional (2D) nanosheet catalyst, Ni/HZ5-NS (50 nm), was synthesized and used to catalyze the selective hydrodeoxygenation of a lignin model compound, 4-ethylguaiacol, to prepare renewable fuel precursors (C8–C16 alkanes). The Ni/HZ5-NS catalyzed conversion of 4-ethylguaiacol to ethyl-cycloalkane reached 100%, and the product selectivity was greater than 95%. The microenvironment of the Ni species in Ni/HZ5-NS was regulated by HZ5-NS. The catalytic activity of Ni/HZ5-NS was twice than that of the traditional Ni/HZ5 catalyst. The high catalytic activity of Ni/HZ5-NS can be attributed to the synergy between the electron-rich Ni and the acidic sites on HZ5-NS but more importantly to the 2D nanosheet structure, which reduces the mass transfer resistance of the system and facilitates molecular diffusion. The application of Ni/HZ5-NS to catalyze C–O bond cleavage was extended to other lignin-derived aromatic ring compounds, and the conversion was found to reach 100%. Importantly cycloalkanes could be obtained with high selectivity. Therefore, this study will be useful for extracting alternative sources of valuable fuel precursors from biomass.

Suggested Citation

  • Lin, Feng & Ma, Yulong & Sun, Yonggang & Song, Zhi & Men, Xiuqin & Wu, Yuhua & Zhu, Yingbo & Gao, Tingting & Zhong, Yudan, 2022. "Selective hydrodeoxygenation of lignin model compound to renewable fuel precursors using two-dimensional nanosheet Ni/HZ5-NS catalyst," Renewable Energy, Elsevier, vol. 189(C), pages 1278-1291.
    • Handle: RePEc:eee:renene:v:189:y:2022:i:c:p:1278-1291
    DOI: 10.1016/j.renene.2022.02.097
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    1. Chuanfu Wang & Lei Zhang & Xin Huang & Yufei Zhu & Gang (Kevin) Li & Qinfen Gu & Jingyun Chen & Linge Ma & Xiujie Li & Qihua He & Junbo Xu & Qi Sun & Chuqiao Song & Mi Peng & Junliang Sun & Ding Ma, 2019. "Maximizing sinusoidal channels of HZSM-5 for high shape-selectivity to p-xylene," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    2. Guan, Weixiang & Chen, Xiao & Zhang, Jie & Hu, Haoquan & Liang, Changhai, 2020. "Catalytic transfer hydrogenolysis of lignin α-O-4 model compound 4-(benzyloxy)phenol and lignin over Pt/HNbWO6/CNTs catalyst," Renewable Energy, Elsevier, vol. 156(C), pages 249-259.
    3. Lin, Feng & Ma, Yulong & Sun, Yonggang & Zhao, Kanghe & Gao, Tingting & Zhu, Yingbo, 2021. "Heterogeneous Ni–Ru/H-ZSM-5 one-pot catalytic conversion of lignin into monophenols," Renewable Energy, Elsevier, vol. 170(C), pages 1070-1080.
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    Cited by:

    1. Zhu, Yingbo & Ma, Yulong & Sun, Yonggang & Wang, Liqiong & Ding, Jie & Zhong, Yudan & Zhang, Juan & Wang, Lei & Li, Yuanyuan, 2023. "In-situ construction of N-doped hollow carbon polyhedral cage anchored Co-Ni dual binding sites as nanoreactor for efficient real lignin oil hydrodeoxygenation," Renewable Energy, Elsevier, vol. 217(C).
    2. Song, Wenjing & Song, Mengxue & Cai, Wenqing & Li, Weichu & Jiang, Xingmao & Fang, Weiping & Lai, Weikun, 2022. "Efficient and stable SiO2-encapsulated NiPt/HY catalyst for catalytic cracking of β-O-4 linkage compound," Renewable Energy, Elsevier, vol. 198(C), pages 334-342.

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    Keywords

    Lignin; Nanosheet; Ni/HZ5; Fuel precursor; Hydrodeoxygenation;
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