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Enhancing sorption kinetics by oriented and single crystalline array-structured ZSM-5 film on monoliths

Author

Listed:
  • Junfei Weng

    (University of Connecticut)

  • Chunxiang Zhu

    (University of Connecticut)

  • Binchao Zhao

    (University of Connecticut)

  • Wenxiang Tang

    (University of Connecticut)

  • Xingxu Lu

    (University of Connecticut)

  • Fangyuan Liu

    (University of Connecticut)

  • Mudi Wu

    (University of Connecticut)

  • Yong Ding

    (Georgia Institute of Technology)

  • Pu-Xian Gao

    (University of Connecticut)

Abstract

To enhance the reaction kinetics without sacrificing activity in porous materials, one potential solution is to utilize the anisotropic distribution of pores and channels besides enriching active centers at the reactive surfaces. Herein, by designing a unique distribution of oriented pores and single crystalline array structures in the presence of abundant acid sites as demonstrated in the ZSM-5 nanorod arrays grown on monoliths, both enhanced dynamics and improved capacity are exhibited simultaneously in propene capture at low temperature within a short duration. Meanwhile, the ZSM-5 array also helps mitigate the long-chain HCs and coking formation due to the enhanced diffusion of reactants in and reaction products out of the array structures. Further integrating the ZSM-5 array with Co3O4 nanoarray enables comprehensive propene removal throughout a wider temperature range. The array structured film design could offer energy-efficient solutions to overcome both sorption and reaction kinetic restrictions in various solid porous materials for various energy and chemical transformation applications.

Suggested Citation

  • Junfei Weng & Chunxiang Zhu & Binchao Zhao & Wenxiang Tang & Xingxu Lu & Fangyuan Liu & Mudi Wu & Yong Ding & Pu-Xian Gao, 2024. "Enhancing sorption kinetics by oriented and single crystalline array-structured ZSM-5 film on monoliths," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-49672-5
    DOI: 10.1038/s41467-024-49672-5
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    References listed on IDEAS

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    1. Son Hoang & Yanbing Guo & Andrew J. Binder & Wenxiang Tang & Sibo Wang & Jingyue (Jimmy) Liu & Huan Tran & Xingxu Lu & Yu Wang & Yong Ding & Eleni A. Kyriakidou & Ji Yang & Todd J. Toops & Thomas R. P, 2020. "Activating low-temperature diesel oxidation by single-atom Pt on TiO2 nanowire array," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
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    4. Minkee Choi & Kyungsu Na & Jeongnam Kim & Yasuhiro Sakamoto & Osamu Terasaki & Ryong Ryoo, 2009. "Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts," Nature, Nature, vol. 461(7261), pages 246-249, September.
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