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Versatile functionalized mesoporous Zr/SBA-15 for catalytic transfer hydrogenation and oxidation reactions

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  • Ostovar, Somayeh
  • Saravani, Hamideh
  • Rodríguez-Padrón, Daily

Abstract

Through this work, a family of sulfonamide functionalized mesoporous materials as sustainable heterogeneous catalysts has been successfully synthesized by employing sulfaguanidine, sulfathiazole, and sulfadiazine. The samples were fully characterized using a multitechnique approach. Such materials have proved to be highly versatile and catalytically active in both the advances in the hydrogenation of Levulinic acid through heterogeneous catalytic transfer hydrogenation (CTH) and oxidation reactions with a strong emphasis on discussing morphology and structure of versatile catalysts, plausible mechanism, and performance of the catalysts for biomass valorization of renewable feedstock. In particular, the prepared catalytic systems were tested in levulinic acid transformation into γ-Valerolactone, achieving a maximum conversion of 99% and a selectivity of 90% for the sulfaguanidine modified sample. The three nanocatalysts displayed good stability over four reuse cycles, and by considering the results of a hot filtration test, it is confirmed that the nature of the catalysis is heterogeneous as acid-base pairs and functionalized groups on catalytic activation of C–H and CO bonds for transfer hydrogenation of levulinic acid. Moreover, such samples also showed remarkable results in the oxidation of benzyl alcohol towards benzaldehyde, with conversion and selectivity values of 95% and 97%, respectively. The obtained catalytic results are highly promising for biomass upgrading processes, looking forward to a more sustainable future.

Suggested Citation

  • Ostovar, Somayeh & Saravani, Hamideh & Rodríguez-Padrón, Daily, 2021. "Versatile functionalized mesoporous Zr/SBA-15 for catalytic transfer hydrogenation and oxidation reactions," Renewable Energy, Elsevier, vol. 178(C), pages 1070-1083.
    • Handle: RePEc:eee:renene:v:178:y:2021:i:c:p:1070-1083
    DOI: 10.1016/j.renene.2021.06.095
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    References listed on IDEAS

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    1. Gaurav, N. & Sivasankari, S. & Kiran, GS & Ninawe, A. & Selvin, J., 2017. "Utilization of bioresources for sustainable biofuels: A Review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 205-214.
    2. Yu, Zhihao & Lu, Xuebin & Liu, Chen & Han, Yiwen & Ji, Na, 2019. "Synthesis of γ-valerolactone from different biomass-derived feedstocks: Recent advances on reaction mechanisms and catalytic systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 112(C), pages 140-157.
    3. Xu, Chunping & Paone, Emilia & Rodríguez-Padrón, Daily & Luque, Rafael & Mauriello, Francesco, 2020. "Reductive catalytic routes towards sustainable production of hydrogen, fuels and chemicals from biomass derived polyols," Renewable and Sustainable Energy Reviews, Elsevier, vol. 127(C).
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    1. Chen, Feiyi & Wang, Yue & Zhang, Junhua & Liu, Huai & Peng, Lincai, 2023. "Construction of HfO2 nanoparticles with rich hydroxyl group for the efficient catalytic transfer hydrogenation of furfural," Renewable Energy, Elsevier, vol. 215(C).
    2. Fang, Juan & Dong, Hao & Xu, Haimei, 2023. "The effect of Lewis acidity of tin loading siliceous MCM-41 on glucose conversion into 5-hydroxymethylfurfural," Renewable Energy, Elsevier, vol. 218(C).

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