IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v177y2021icp652-662.html
   My bibliography  Save this article

Highly efficient g-C3N4 supported ruthenium catalysts for the catalytic transfer hydrogenation of levulinic acid to liquid fuel γ-valerolactone

Author

Listed:
  • Cai, Bo
  • Zhang, Yongjian
  • Feng, Junfeng
  • Huang, Cong
  • Ma, Tianyi
  • Pan, Hui

Abstract

Gamma-valerolactone (GVL) is a versatile building block compound with wide applications and it can be obtained from biomass-derived chemical levulinic acid (LA). In this study, graphite carbon nitride (g-C3N4) were prepared from two different precursors (urea and melamine) and used as the support to anchor ruthenium (Ru) nanoparticle (Ru/g-C3N4) for catalytic transfer hydrogenation of LA to GVL. The resulting catalyst prepared from urea precursor (Ru/UCN) showed 100% LA conversion and nearly theoretic GVL yield of 99.8% under mild condition. Detailed characterizations of the Ru/g-C3N4 suggested that Ru showed different interactions with the g-C3N4 supports from two different precursors. Ru nanoparticles exhibited smaller size and better dispersion on the g-C3N4 support from urea (UCN) than that from melamine (MCN). The XPS result indicated that more electron rich Ru0 species on the Ru/UCN catalyst also contributed to the higher catalytic activity of the Ru/UCN. Furthermore, the Ru/UCN catalyst was demonstrated high stability in acidic reaction medium and remained highly reactive after recycled for 5 times.

Suggested Citation

  • Cai, Bo & Zhang, Yongjian & Feng, Junfeng & Huang, Cong & Ma, Tianyi & Pan, Hui, 2021. "Highly efficient g-C3N4 supported ruthenium catalysts for the catalytic transfer hydrogenation of levulinic acid to liquid fuel γ-valerolactone," Renewable Energy, Elsevier, vol. 177(C), pages 652-662.
    • Handle: RePEc:eee:renene:v:177:y:2021:i:c:p:652-662
    DOI: 10.1016/j.renene.2021.05.159
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S096014812100848X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2021.05.159?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Cao, Xincheng & Long, Feng & Zhai, Qiaolong & Liu, Peng & Xu, Junming & Jiang, Jianchun, 2020. "Enhancement of fatty acids hydrodeoxygenation selectivity to diesel-range alkanes over the supported Ni-MoOx catalyst and elucidation of the active phase," Renewable Energy, Elsevier, vol. 162(C), pages 2113-2125.
    2. Wei Liu & Wenqin You & Wei Sun & Weisheng Yang & Akshay Korde & Yutao Gong & Yulin Deng, 2020. "Ambient-pressure and low-temperature upgrading of lignin bio-oil to hydrocarbons using a hydrogen buffer catalytic system," Nature Energy, Nature, vol. 5(10), pages 759-767, October.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Cai, Bo & Kang, Rui & Guo, Dayi & Feng, Junfeng & Ma, Tianyi & Pan, Hui, 2022. "An eco-friendly acidic catalyst phosphorus-doped graphitic carbon nitride for efficient conversion of fructose to 5-Hydroxymethylfurfural," Renewable Energy, Elsevier, vol. 199(C), pages 1629-1638.
    2. Anagnostopoulou, Eleni & Lilas, Panagiotis & Diamantopoulou, Perikleia & Fakas, Christos & Krithinakis, Ioannis & Patatsi, Eleni & Gabrielatou, Elpida & van Muyden, Antoine P. & Dyson, Paul J. & Papad, 2022. "Hydrogenation of the pivotal biorefinery platform molecule levulinic acid into renewable fuel γ-valerolactone catalyzed by unprecedented highly active and stable ruthenium nanoparticles in aqueous med," Renewable Energy, Elsevier, vol. 192(C), pages 35-45.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Tao Peng & Wenbin Zhang & Baiyao Liang & Guanwu Lian & Yun Zhang & Wei Zhao, 2023. "Electrocatalytic valorization of lignocellulose-derived aromatics at industrial-scale current densities," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    2. Li, Xingyong & Fan, Qiyuan & Wu, Kaiyue & Liu, Na & Zhang, Wei & Liu, Ying & Chen, Yubao & Cheng, Jun & Zheng, Zhifeng, 2024. "Enhancing catalytic isomerization ability of SAPO-11 by typical acid modification in preparation of green diesel by one-step hydrotreatment of FAME," Renewable Energy, Elsevier, vol. 224(C).
    3. Li, Chang & Wang, Yishuang & Tang, Zhiyuan & Zhou, Zinan & Qin, Baolong & Chen, Mingqiang, 2023. "The bifunctional active sites on carbon supported Fe-Mo bimetallic catalyst to improve Kraft lignin liquefaction," Renewable Energy, Elsevier, vol. 219(P2).
    4. Wang, Jingyi & Ren, Dezhang & Zhang, Nahui & Lang, Junyu & Du, Yueying & He, Wenhui & Norinaga, Koyo & Huo, Zhibao, 2023. "Boosting in-situ hydrodeoxygenation of fatty acids over a fine and oxygen-vacancy-rich NiAl catalyst," Renewable Energy, Elsevier, vol. 202(C), pages 952-960.
    5. Cao, Yang & He, Mingjing & Dutta, Shanta & Luo, Gang & Zhang, Shicheng & Tsang, Daniel C.W., 2021. "Hydrothermal carbonization and liquefaction for sustainable production of hydrochar and aromatics," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    6. Cai, Bo & Kang, Rui & Guo, Dayi & Feng, Junfeng & Ma, Tianyi & Pan, Hui, 2022. "An eco-friendly acidic catalyst phosphorus-doped graphitic carbon nitride for efficient conversion of fructose to 5-Hydroxymethylfurfural," Renewable Energy, Elsevier, vol. 199(C), pages 1629-1638.
    7. Zhang, Yu & Jiang, Haifeng & Li, Yuhang & Jia, Wei & Song, Meng & Hong, Wenpeng, 2024. "Efficient production of furans by CO2-assisted pyrolysis of cellulose with carbon-supported Ni/Co catalysts," Energy, Elsevier, vol. 294(C).
    8. Tang, Hongbiao & Lin, Jiayu & Cao, Yang & Jibran, Khalil & Li, Jin, 2022. "Influence of NiMoP phase on hydrodeoxygenation pathways of jatropha oil," Energy, Elsevier, vol. 243(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:177:y:2021:i:c:p:652-662. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.