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Biomass waste conversion into value-added products via microwave-assisted Co-Pyrolysis platform

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  • Suriapparao, Dadi V.
  • Vinu, R.

Abstract

The current work is focused to investigate the synergetic interactions between biomass (groundnut shell, bagasse, rice husk, Prosopis juliflora, mixed wood sawdust) and hydro-rich plastics (Low-density polyethylene (LDPE) and Polyisoprene (PIP)) in microwave co-pyrolysis. The heating value of co-pyrolysis oil (38–42 MJ kg−1) was enhanced dramatically compared to biomass pyrolysis oil (20–28 MJ kg−1). Among biomasses studied, the energy yield of bio-oil obtained from rice husk with LDPE mixture is higher (42%). Whereas bio-oil from polyisoprene and groundnut shell mixture has the highest energy yield (78%). Each gram of co-pyrolysis feedstock consumed 12–18 kJ of incident microwave energy. An increase in overall energy efficiency in co-pyrolysis (62–70%) is observed compared to that of biomass pyrolysis (46–57%). Actual mass yield (31–47 wt%) of co-pyrolysis bio-crude is lower than its predicted value (42–57 wt%) due to the formation of lighter gases. In the combinations of and hydrogen-rich plastics considered in this study, it was found that co-pyrolysis of LDPE: bagasse has produced bio-crude with the highest yield of aliphatic hydrocarbons (25.78%), and co-pyrolysis of LDPE: rice husk has produced bio-crude with high selectivity of aromatics (11.7%). The extent of de-oxygenation was promoted in the co-pyrolysis due to synergy.

Suggested Citation

  • Suriapparao, Dadi V. & Vinu, R., 2021. "Biomass waste conversion into value-added products via microwave-assisted Co-Pyrolysis platform," Renewable Energy, Elsevier, vol. 170(C), pages 400-409.
    • Handle: RePEc:eee:renene:v:170:y:2021:i:c:p:400-409
    DOI: 10.1016/j.renene.2021.02.010
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    Citations

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    Cited by:

    1. Xu, Donghua & Lin, Junhao & Ma, Rui & Fang, Lin & Sun, Shichang & Luo, Juan, 2022. "Microwave pyrolysis of biomass for low-oxygen bio-oil: Mechanisms of CO2-assisted in-situ deoxygenation," Renewable Energy, Elsevier, vol. 184(C), pages 124-133.
    2. Dessì, Federica & Mureddu, Mauro & Ferrara, Francesca & Pettinau, Alberto, 2022. "A comprehensive pathway on the determination of the kinetic triplet and the reaction mechanism of brewer's spent grain and beech wood chips pyrolysis," Renewable Energy, Elsevier, vol. 190(C), pages 548-559.
    3. Suriapparao, Dadi V. & Hemanth Kumar, Tanneru & Reddy, B. Rajasekhar & Yerrayya, Attada & Srinivas, B. Abhinaya & Sivakumar, Pandian & Prakash, S. Reddy & Sankar Rao, Chinta & Sridevi, Veluru & Desing, 2022. "Role of ZSM5 catalyst and char susceptor on the synthesis of chemicals and hydrocarbons from microwave-assisted in-situ catalytic co-pyrolysis of algae and plastic wastes," Renewable Energy, Elsevier, vol. 181(C), pages 990-999.
    4. Krystian Butlewski, 2022. "Concept for Biomass and Organic Waste Refinery Plants Based on the Locally Available Organic Materials in Rural Areas of Poland," Energies, MDPI, vol. 15(9), pages 1-19, May.
    5. Nabila, Rakhmawati & Hidayat, Wahyu & Haryanto, Agus & Hasanudin, Udin & Iryani, Dewi Agustina & Lee, Sihyun & Kim, Sangdo & Kim, Soohyun & Chun, Donghyuk & Choi, Hokyung & Im, Hyuk & Lim, Jeonghwan &, 2023. "Oil palm biomass in Indonesia: Thermochemical upgrading and its utilization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 176(C).
    6. Tatyana Iglina & Pavel Iglin & Dmitry Pashchenko, 2022. "Industrial CO 2 Capture by Algae: A Review and Recent Advances," Sustainability, MDPI, vol. 14(7), pages 1-26, March.
    7. I. Fernández & S. F. Pérez & J. Fernández-Ferreras & T. Llano, 2024. "Microwave-Assisted Pyrolysis of Forest Biomass," Energies, MDPI, vol. 17(19), pages 1-34, September.

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