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Hydrothermal carbonization of waste biomass to fuel: A novel technique for analyzing experimental data

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  • Gallifuoco, Alberto
  • Taglieri, Luca
  • Papa, Alessandro Antonio

Abstract

This paper deals with a new stochastic approach to handling data from waste biomass hydrothermal carbonization. The dynamics of hydrochar properties are described using the concept of reaction time distributions. A set of cumulative frequency distribution functions is provided that could very well correlate the most disparate experimental data. The procedure for analyzing the results is detailed. The method is illustrated with experiments on batch runs with five different wastes from the agro-food industry. Isothermal reactions (200 °C) were performed up to 120 min at a constant 7/1 water/biomass ratio. The regression analyses fully confirm the correctness of the method. The use of dynamical van Krevelen plots is proposed. The approach allows also obtaining from lab-scale runs fundamental information for the correct waste-to-fuel process development at the industrial scale. The mathematics is not demanding and, unlike other methods, the difficulties substantially do not increase with the complexity of the modeled kinetic scheme.

Suggested Citation

  • Gallifuoco, Alberto & Taglieri, Luca & Papa, Alessandro Antonio, 2020. "Hydrothermal carbonization of waste biomass to fuel: A novel technique for analyzing experimental data," Renewable Energy, Elsevier, vol. 149(C), pages 1254-1260.
    • Handle: RePEc:eee:renene:v:149:y:2020:i:c:p:1254-1260
    DOI: 10.1016/j.renene.2019.10.121
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    References listed on IDEAS

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    1. Zhao, Peitao & Shen, Yafei & Ge, Shifu & Chen, Zhenqian & Yoshikawa, Kunio, 2014. "Clean solid biofuel production from high moisture content waste biomass employing hydrothermal treatment," Applied Energy, Elsevier, vol. 131(C), pages 345-367.
    2. Silvia Román & Judy Libra & Nicole Berge & Eduardo Sabio & Kyoung Ro & Liang Li & Beatriz Ledesma & Andrés Álvarez & Sunyoung Bae, 2018. "Hydrothermal Carbonization: Modeling, Final Properties Design and Applications: A Review," Energies, MDPI, vol. 11(1), pages 1-28, January.
    3. He, Chao & Tang, Chunyan & Li, Chuanhao & Yuan, Jihui & Tran, Khanh-Quang & Bach, Quang-Vu & Qiu, Rongliang & Yang, Yanhui, 2018. "Wet torrefaction of biomass for high quality solid fuel production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 259-271.
    4. Munir, M. Tajammal & Mansouri, Seyed Soheil & Udugama, Isuru A. & Baroutian, Saeid & Gernaey, Krist V. & Young, Brent R., 2018. "Resource recovery from organic solid waste using hydrothermal processing: Opportunities and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 96(C), pages 64-75.
    5. He, Chao & Giannis, Apostolos & Wang, Jing-Yuan, 2013. "Conversion of sewage sludge to clean solid fuel using hydrothermal carbonization: Hydrochar fuel characteristics and combustion behavior," Applied Energy, Elsevier, vol. 111(C), pages 257-266.
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