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Fabrication of noble-metal-free CdS nanorods-carbon layer-cobalt phosphide multiple heterojunctions for efficient and robust photocatalyst hydrogen evolution under visible light irradiation

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  • Wang, Peifang
  • Wu, Tengfei
  • Ao, Yanhui
  • Wang, Chao

Abstract

Photocatalytic water splitting has aroused great interest as a clean and renewable energy conversion process. In this study, we prepared a novel noble-metal-free multiple heterojunction photocatalyst (CdS@C-CoP) composed of CdS nanorods, conducting carbon layer and CoP nanoparticles cocatalyst for the first time. The obtained CdS@C-CoP composites exhibited excellent performance and stability under visible light irradiation when it was used as photocatalysts for hydrogen evolution. For the optimum CdS@C-CoP sample, an average hydrogen evolution rate reached up to 10089 μmol g−1 h−1, nearly 6 fold as high as that of pure CdS. The enhanced photocatalytic hydrogen production rate can be ascribed to the synergistic effect between conductive carbon layer and surface cocatalyst CoP, which resulted in efficient separation of photoexcited charge carriers and abundant active sites for hydrogen reduction. This work presented a novel way to design composite photocatalyst with efficient hydrogen generation properties through combining two kinds of surface modification methods: thin carbon layer coating and surface cocatalysts loading.

Suggested Citation

  • Wang, Peifang & Wu, Tengfei & Ao, Yanhui & Wang, Chao, 2019. "Fabrication of noble-metal-free CdS nanorods-carbon layer-cobalt phosphide multiple heterojunctions for efficient and robust photocatalyst hydrogen evolution under visible light irradiation," Renewable Energy, Elsevier, vol. 131(C), pages 180-186.
  • Handle: RePEc:eee:renene:v:131:y:2019:i:c:p:180-186
    DOI: 10.1016/j.renene.2018.07.028
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    References listed on IDEAS

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    1. Yuval Ben-Shahar & Francesco Scotognella & Ilka Kriegel & Luca Moretti & Giulio Cerullo & Eran Rabani & Uri Banin, 2016. "Optimal metal domain size for photocatalysis with hybrid semiconductor-metal nanorods," Nature Communications, Nature, vol. 7(1), pages 1-7, April.
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    Cited by:

    1. Li, Yanbing & Zhu, Pengfei & Tsubaki, Noritatsu & Jin, Zhiliang, 2022. "Fabrication of hierarchical CoP/ZnCdS/Co3O4 quantum dots (800>40>4.5 nm) bi-heterostructure cages for efficient photocatalytic hydrogen evolution," Renewable Energy, Elsevier, vol. 198(C), pages 626-636.
    2. Ding, Haoran & Xu, Mengyu & Zhang, Shicong & Yu, Fengtao & Kong, Kangyi & Shen, Zhongjin & Hua, Jianli, 2020. "Organic blue-colored D-A-π-A dye-sensitized TiO2 for efficient and stable photocatalytic hydrogen evolution under visible/near-infrared-light irradiation," Renewable Energy, Elsevier, vol. 155(C), pages 1051-1059.
    3. Li, Hongying & Gong, Haiming & Hao, Xuqiang & Wang, Guorong & Jin, Zhiliang, 2022. "Phosphating MIL-53(Fe) as cocatalyst modified porous NiTiO3 for photocatalytic hydrogen production," Renewable Energy, Elsevier, vol. 188(C), pages 132-144.
    4. Bai, Ping & Lang, Junyu & Wang, Yinshu & Tong, Haojie & Wang, Zelin & Zhang, Bingbing & Su, Yiguo & Chai, Zhanli, 2024. "Z-scheme ZnCdS/NiCo-LDH photocatalyst followed dual-channel charge transfer via Au-intercalation for renewable hydrogen production," Renewable Energy, Elsevier, vol. 226(C).
    5. Pan, Jiaqi & Li, Hongli & Li, Shi & Ou, Wei & Liu, Yanyan & Wang, Jingjing & Song, Changsheng & Zheng, Yingying & Li, Chaorong, 2020. "The enhanced photocatalytic hydrogen production of nickel-cobalt bimetals sulfide synergistic modified CdS nanorods with active facets," Renewable Energy, Elsevier, vol. 156(C), pages 469-477.

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