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Renewable gasoline production from oleic acid by oxidative cleavage followed by decarboxylation

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  • Sembiring, Kiky Corneliasari
  • Aunillah, Asif
  • Minami, Eiji
  • Saka, Shiro

Abstract

Hydrocarbons in a range of the renewable gasoline chain-length were produced by oxidative cleavage of unsaturated fatty acid, oleic acid, followed by decarboxylation. The effects of the emulsifier, concentration of oxidizing agent, reaction temperature, and atmospheric conditions were investigated. As a result, the optimum condition was found for oxidative cleavage to be 1.0 wt% emulsifier, KMnO4/oleic acid = 4/1 (mol/mol), at 40 °C, for 30 min to obtain about 93 mol% pelargonic acid (C9 monocarboxylic acid) and 86 mol% azelaic acid (C9 dicarboxylic acid). Decarboxylation of these obtained short-chain fatty acids, pelargonic and azelaic acids, gave 98.2 mol% n-octane (C8) and 73.1 mol% n-heptane (C7), respectively, under the appropriate conditions of 300 °C/10 MPa and 300 °C/5 MPa (N2 pressure) with 6 mol% Pd/C for 2–3 h. Although decarboxylation of azelaic acid resulted in lower yield, the obtained results highlight a potential of plant oil conversion to hydrocarbons as renewable gasoline.

Suggested Citation

  • Sembiring, Kiky Corneliasari & Aunillah, Asif & Minami, Eiji & Saka, Shiro, 2018. "Renewable gasoline production from oleic acid by oxidative cleavage followed by decarboxylation," Renewable Energy, Elsevier, vol. 122(C), pages 602-607.
  • Handle: RePEc:eee:renene:v:122:y:2018:i:c:p:602-607
    DOI: 10.1016/j.renene.2018.01.107
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    References listed on IDEAS

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    1. Pattanaik, Bhabani Prasanna & Misra, Rahul Dev, 2017. "Effect of reaction pathway and operating parameters on the deoxygenation of vegetable oils to produce diesel range hydrocarbon fuels: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 545-557.
    2. Araújo, Aruzza Mabel de Morais & Lima, Regineide de Oliveira & Gondim, Amanda Duarte & Diniz, Juraci & Souza, Luiz Di & Araujo, Antonio Souza de, 2017. "Thermal and catalytic pyrolysis of sunflower oil using AlMCM-41," Renewable Energy, Elsevier, vol. 101(C), pages 900-906.
    3. Tanneru, Sathish K. & Steele, Philip H., 2015. "Production of liquid hydrocarbons from pretreated bio-oil via catalytic deoxygenation with syngas," Renewable Energy, Elsevier, vol. 80(C), pages 251-258.
    4. Balat, Mustafa & Balat, Havva, 2009. "Recent trends in global production and utilization of bio-ethanol fuel," Applied Energy, Elsevier, vol. 86(11), pages 2273-2282, November.
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