IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v122y2018icp602-607.html
   My bibliography  Save this article

Renewable gasoline production from oleic acid by oxidative cleavage followed by decarboxylation

Author

Listed:
  • Sembiring, Kiky Corneliasari
  • Aunillah, Asif
  • Minami, Eiji
  • Saka, Shiro

Abstract

Hydrocarbons in a range of the renewable gasoline chain-length were produced by oxidative cleavage of unsaturated fatty acid, oleic acid, followed by decarboxylation. The effects of the emulsifier, concentration of oxidizing agent, reaction temperature, and atmospheric conditions were investigated. As a result, the optimum condition was found for oxidative cleavage to be 1.0 wt% emulsifier, KMnO4/oleic acid = 4/1 (mol/mol), at 40 °C, for 30 min to obtain about 93 mol% pelargonic acid (C9 monocarboxylic acid) and 86 mol% azelaic acid (C9 dicarboxylic acid). Decarboxylation of these obtained short-chain fatty acids, pelargonic and azelaic acids, gave 98.2 mol% n-octane (C8) and 73.1 mol% n-heptane (C7), respectively, under the appropriate conditions of 300 °C/10 MPa and 300 °C/5 MPa (N2 pressure) with 6 mol% Pd/C for 2–3 h. Although decarboxylation of azelaic acid resulted in lower yield, the obtained results highlight a potential of plant oil conversion to hydrocarbons as renewable gasoline.

Suggested Citation

  • Sembiring, Kiky Corneliasari & Aunillah, Asif & Minami, Eiji & Saka, Shiro, 2018. "Renewable gasoline production from oleic acid by oxidative cleavage followed by decarboxylation," Renewable Energy, Elsevier, vol. 122(C), pages 602-607.
    • Handle: RePEc:eee:renene:v:122:y:2018:i:c:p:602-607
    DOI: 10.1016/j.renene.2018.01.107
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148118301174
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2018.01.107?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Pattanaik, Bhabani Prasanna & Misra, Rahul Dev, 2017. "Effect of reaction pathway and operating parameters on the deoxygenation of vegetable oils to produce diesel range hydrocarbon fuels: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 545-557.
    2. Balat, Mustafa & Balat, Havva, 2009. "Recent trends in global production and utilization of bio-ethanol fuel," Applied Energy, Elsevier, vol. 86(11), pages 2273-2282, November.
    3. Araújo, Aruzza Mabel de Morais & Lima, Regineide de Oliveira & Gondim, Amanda Duarte & Diniz, Juraci & Souza, Luiz Di & Araujo, Antonio Souza de, 2017. "Thermal and catalytic pyrolysis of sunflower oil using AlMCM-41," Renewable Energy, Elsevier, vol. 101(C), pages 900-906.
    4. Tanneru, Sathish K. & Steele, Philip H., 2015. "Production of liquid hydrocarbons from pretreated bio-oil via catalytic deoxygenation with syngas," Renewable Energy, Elsevier, vol. 80(C), pages 251-258.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Filimonau, Viachaslau & Högström, Michaela, 2017. "The attitudes of UK tourists to the use of biofuels in civil aviation: An exploratory study," Journal of Air Transport Management, Elsevier, vol. 63(C), pages 84-94.
    2. Yasuda, Masahide & Matsumoto, Tomoko & Yamashita, Toshiaki, 2018. "Sacrificial hydrogen production over TiO2-based photocatalysts: Polyols, carboxylic acids, and saccharides," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 1627-1635.
    3. Bharathiraja, B. & Jayamuthunagai, J. & Sudharsanaa, T. & Bharghavi, A. & Praveenkumar, R. & Chakravarthy, M. & Yuvaraj, D., 2017. "Biobutanol – An impending biofuel for future: A review on upstream and downstream processing tecniques," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P1), pages 788-807.
    4. Zhang, Chen & Sun, Zongxuan, 2017. "Trajectory-based combustion control for renewable fuels in free piston engines," Applied Energy, Elsevier, vol. 187(C), pages 72-83.
    5. Andrea Patané & Giorgio Jansen & Piero Conca & Giovanni Carapezza & Jole Costanza & Giuseppe Nicosia, 2019. "Multi-objective optimization of genome-scale metabolic models: the case of ethanol production," Annals of Operations Research, Springer, vol. 276(1), pages 211-227, May.
    6. M'Arimi, M.M. & Mecha, C.A. & Kiprop, A.K. & Ramkat, R., 2020. "Recent trends in applications of advanced oxidation processes (AOPs) in bioenergy production: Review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 121(C).
    7. Sánchez, S. & Lozano, L.J. & Godínez, C. & Juan, D. & Pérez, A. & Hernández, F.J., 2010. "Carob pod as a feedstock for the production of bioethanol in Mediterranean areas," Applied Energy, Elsevier, vol. 87(11), pages 3417-3424, November.
    8. Jin, Wenxiang & Chen, Ling & Hu, Meng & Sun, Dan & Li, Ao & Li, Ying & Hu, Zhen & Zhou, Shiguang & Tu, Yuanyuan & Xia, Tao & Wang, Yanting & Xie, Guosheng & Li, Yanbin & Bai, Baowei & Peng, Liangcai, 2016. "Tween-80 is effective for enhancing steam-exploded biomass enzymatic saccharification and ethanol production by specifically lessening cellulase absorption with lignin in common reed," Applied Energy, Elsevier, vol. 175(C), pages 82-90.
    9. Diep, Nhu Quynh & Fujimoto, Shinji & Minowa, Tomoaki & Sakanishi, Kinya & Nakagoshi, Nobukazu, 2012. "Estimation of the potential of rice straw for ethanol production and the optimum facility size for different regions in Vietnam," Applied Energy, Elsevier, vol. 93(C), pages 205-211.
    10. Phanankosi Moyo & Mahluli Moyo & Donatus Dube & Oswell Rusinga, 2013. "Biofuel Policy as a Key Driver for Sustainable Development in the Biofuel Sector: The Missing Ingredient in Zimbabwe’s Biofuel Pursuit," Modern Applied Science, Canadian Center of Science and Education, vol. 8(1), pages 1-36, February.
    11. Tan, Raymond R. & Aviso, Kathleen B. & Barilea, Ivan U. & Culaba, Alvin B. & Cruz, Jose B., 2012. "A fuzzy multi-regional input–output optimization model for biomass production and trade under resource and footprint constraints," Applied Energy, Elsevier, vol. 90(1), pages 154-160.
    12. Yao, Yung-Chen & Tsai, Jiun-Horng & Wang, I-Ting, 2013. "Emissions of gaseous pollutant from motorcycle powered by ethanol–gasoline blend," Applied Energy, Elsevier, vol. 102(C), pages 93-100.
    13. Arkadiusz Piwowar & Maciej Dzikuć, 2019. "Development of Renewable Energy Sources in the Context of Threats Resulting from Low-Altitude Emissions in Rural Areas in Poland: A Review," Energies, MDPI, vol. 12(18), pages 1-15, September.
    14. Lenka Rumánková & Luboš Smutka, 2013. "Global sugar market - the analysis of factors influencing supply and demand," Acta Universitatis Agriculturae et Silviculturae Mendelianae Brunensis, Mendel University Press, vol. 61(2), pages 463-471.
    15. Starfelt, Fredrik & Daianova, Lilia & Yan, Jinyue & Thorin, Eva & Dotzauer, Erik, 2012. "The impact of lignocellulosic ethanol yields in polygeneration with district heating – A case study," Applied Energy, Elsevier, vol. 92(C), pages 791-799.
    16. Akroum-Amrouche, Dahbia & Abdi, Nadia & Lounici, Hakim & Mameri, Nabil, 2011. "Effect of physico-chemical parameters on biohydrogen production and growth characteristics by batch culture of Rhodobacter sphaeroides CIP 60.6," Applied Energy, Elsevier, vol. 88(6), pages 2130-2135, June.
    17. Vallinayagam, R. & Vedharaj, S. & Yang, W.M. & Roberts, W.L. & Dibble, R.W., 2015. "Feasibility of using less viscous and lower cetane (LVLC) fuels in a diesel engine: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 1166-1190.
    18. Aloisio S. Nascimento Filho & Rafael G. O. dos Santos & João Gabriel A. Calmon & Peterson A. Lobato & Marcelo A. Moret & Thiago B. Murari & Hugo Saba, 2022. "Induction of a Consumption Pattern for Ethanol and Gasoline in Brazil," Sustainability, MDPI, vol. 14(15), pages 1-11, July.
    19. Katia A. Figueroa-Rodríguez & Francisco Hernández-Rosas & Benjamín Figueroa-Sandoval & Joel Velasco-Velasco & Noé Aguilar Rivera, 2019. "What Has Been the Focus of Sugarcane Research? A Bibliometric Overview," IJERPH, MDPI, vol. 16(18), pages 1-15, September.
    20. Poder, Thomas G. & He, Jie, 2017. "Willingness to pay for a cleaner car: The case of car pollution in Quebec and France," Energy, Elsevier, vol. 130(C), pages 48-54.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:122:y:2018:i:c:p:602-607. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.