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Surface silanation of alumina-silica zeolites for adsorption heat pumping

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  • Bonaccorsi, Lucio
  • Calabrese, Luigi
  • Alioto, Serena
  • Bruzzaniti, Paolo
  • Proverbio, Edoardo

Abstract

Alumino-silica zeolites A, X and Y have been synthesized and reacted with organosilane compounds. The effect of the silane chemisorption on the zeolites surface has been evaluated by vacuum water adsorption measurements. Results showed that in certain conditions the original hydrophilic character was partially attenuated, demonstrated by a shift in the adsorption isotherms towards a more hydrophobic behavior. The best results were obtained for zeolite 4A modified with dimethoxydimethyl silane and zeolite 13X modified with propyltrimethoxy silane.

Suggested Citation

  • Bonaccorsi, Lucio & Calabrese, Luigi & Alioto, Serena & Bruzzaniti, Paolo & Proverbio, Edoardo, 2017. "Surface silanation of alumina-silica zeolites for adsorption heat pumping," Renewable Energy, Elsevier, vol. 110(C), pages 79-86.
    • Handle: RePEc:eee:renene:v:110:y:2017:i:c:p:79-86
    DOI: 10.1016/j.renene.2016.09.030
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    References listed on IDEAS

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    1. Zheng, X. & Wang, R.Z. & Ge, T.S. & Hu, L.M., 2015. "Performance study of SAPO-34 and FAPO-34 desiccants for desiccant coated heat exchanger systems," Energy, Elsevier, vol. 93(P1), pages 88-94.
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    1. Freni, A. & Calabrese, L. & Malara, A. & Frontera, P. & Bonaccorsi, L., 2019. "Silica gel microfibres by electrospinning for adsorption chillers," Energy, Elsevier, vol. 187(C).
    2. Feng, Changling & E, Jiaqiang & Han, Wei & Deng, Yuanwang & Zhang, Bin & Zhao, Xiaohuan & Han, Dandan, 2021. "Key technology and application analysis of zeolite adsorption for energy storage and heat-mass transfer process: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 144(C).
    3. Chen, Tingting & Xue, Bing & He, Xiaoran & Wei, Ruixun & Li, Guangyao, 2024. "Water-free surface silanization on composite zeolite 13X/MgSO4 in a direct-contact adsorption heat pump for stable steam generation," Renewable Energy, Elsevier, vol. 221(C).

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