IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v109y2017icp188-194.html
   My bibliography  Save this article

Removal of H2S and CO2 from biogas in bench scale and the pilot scale using a regenerable Fe-EDTA solution

Author

Listed:
  • Schiavon Maia, Djeine Cristina
  • Niklevicz, Rafael R.
  • Arioli, Rafael
  • Frare, Laercio M.
  • Arroyo, Pedro A.
  • Gimenes, Marcelino L.
  • Pereira, Nehemias C.

Abstract

Although the hydrogen sulfide is present in small quantities in biogas, it’s a highly toxic and corrosive gas. Through the process of absorption with Fe-EDTA solution, H2S can be eliminated from gas flows, forming elemental sulfur. Another constituent of biogas is the CO2, it can be considered inert and it reduces energy efficiency. In this sense, this work presents a stage in bench scale with synthetic biogas and the pilot scale, of H2S from biogas purification provided of the residual biomass treatment. Both the systems utilize H2S removal method with Fe-EDTA solution produced from commercial inputs, while the CO2 is also physically absorbed in this solution. Experiments were carried out in order to find a great ratio L/G, Fe-EDTA liquid flow by gas flow, due to different Fe-EDTA concentrations. According to CCRD methodology, both bench scale and pilot scale, higher H2S removal efficiencies are obtained for high values of L/G and Fe-EDTA concentration. In bench scale using Fe-EDTA 0.2 mol L−1 and L/G 1.27, H2S removal efficiency was 99% after 35 min. On a pilot scale it was possible to obtain maximum H2S removal of 98% with CO2 removal 18%, thus, there was an increase of 17% in biogas calorific power.

Suggested Citation

  • Schiavon Maia, Djeine Cristina & Niklevicz, Rafael R. & Arioli, Rafael & Frare, Laercio M. & Arroyo, Pedro A. & Gimenes, Marcelino L. & Pereira, Nehemias C., 2017. "Removal of H2S and CO2 from biogas in bench scale and the pilot scale using a regenerable Fe-EDTA solution," Renewable Energy, Elsevier, vol. 109(C), pages 188-194.
  • Handle: RePEc:eee:renene:v:109:y:2017:i:c:p:188-194
    DOI: 10.1016/j.renene.2017.03.023
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148117302045
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.renene.2017.03.023?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Reddy, K.S. & Aravindhan, S. & Mallick, Tapas K., 2016. "Investigation of performance and emission characteristics of a biogas fuelled electric generator integrated with solar concentrated photovoltaic system," Renewable Energy, Elsevier, vol. 92(C), pages 233-243.
    2. Colmenar-Santos, Antonio & Zarzuelo-Puch, Gloria & Borge-Diez, David & García-Diéguez, Concepción, 2016. "Thermodynamic and exergoeconomic analysis of energy recovery system of biogas from a wastewater treatment plant and use in a Stirling engine," Renewable Energy, Elsevier, vol. 88(C), pages 171-184.
    3. Ribeiro, Maria de Fátima dos Santos & Raiher, Augusta Pelinski, 2013. "Potentialities of energy generation from waste and feedstock produced by the agricultural sector in Brazil: The case of the State of Paraná," Energy Policy, Elsevier, vol. 60(C), pages 208-216.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Joanna K. Huertas & Lawrence Quipuzco & Amro Hassanein & Stephanie Lansing, 2020. "Comparing Hydrogen Sulfide Removal Efficiency in a Field-Scale Digester Using Microaeration and Iron Filters," Energies, MDPI, vol. 13(18), pages 1-14, September.
    2. Pallavicini, Jacopo & Fedeli, Matteo & Scolieri, Giacomo Domenico & Tagliaferri, Francesca & Parolin, Jacopo & Sironi, Selena & Manenti, Flavio, 2023. "Digital twin-based optimization and demo-scale validation of absorption columns using sodium hydroxide/water mixtures for the purification of biogas streams subject to impurity fluctuations," Renewable Energy, Elsevier, vol. 219(P1).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ferraz de Campos, Victor Arruda & Silva, Valter Bruno & Cardoso, João Sousa & Brito, Paulo S. & Tuna, Celso Eduardo & Silveira, José Luz, 2021. "A review of waste management in Brazil and Portugal: Waste-to-energy as pathway for sustainable development," Renewable Energy, Elsevier, vol. 178(C), pages 802-820.
    2. Julio Cesar Silva Junior & Andrei Lucas Michaelsen & Mauro Scalvi & Miguel Gomes Pacheco, 2020. "Forecast of electric energy generation potential from swine manure in Santa Catarina, Brazil," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 22(3), pages 2305-2319, March.
    3. Colmenar-Santos, Antonio & Gómez-Camazón, David & Rosales-Asensio, Enrique & Blanes-Peiró, Jorge-Juan, 2018. "Technological improvements in energetic efficiency and sustainability in existing combined-cycle gas turbine (CCGT) power plants," Applied Energy, Elsevier, vol. 223(C), pages 30-51.
    4. Hossein Heirani & Naser Bagheri Moghaddam & Sina Labbafi & Seyedali Sina, 2022. "A Business Model for Developing Distributed Photovoltaic Systems in Iran," Sustainability, MDPI, vol. 14(18), pages 1-21, September.
    5. Nami, Hossein & Anvari-Moghaddam, Amjad, 2020. "Geothermal driven micro-CCHP for domestic application – Exergy, economic and sustainability analysis," Energy, Elsevier, vol. 207(C).
    6. Baran, Burhan & Mamis, Mehmet Salih & Alagoz, Baris Baykant, 2016. "Utilization of energy from waste potential in Turkey as distributed secondary renewable energy source," Renewable Energy, Elsevier, vol. 90(C), pages 493-500.
    7. Buliński, Zbigniew & Szczygieł, Ireneusz & Krysiński, Tomasz & Stanek, Wojciech & Czarnowska, Lucyna & Gładysz, Paweł & Kabaj, Adam, 2017. "Finite time thermodynamic analysis of small alpha-type Stirling engine in non-ideal polytropic conditions for recovery of LNG cryogenic exergy," Energy, Elsevier, vol. 141(C), pages 2559-2571.
    8. Dumitrascu Gheorghe & Feidt Michel & Popescu Aristotel & Grigorean Stefan, 2019. "Endoreversible Trigeneration Cycle Design Based on Finite Physical Dimensions Thermodynamics," Energies, MDPI, vol. 12(16), pages 1-21, August.
    9. İncili, Veysel & Karaca Dolgun, Gülşah & Keçebaş, Ali & Ural, Tolga, 2023. "Energy and exergy analyses of a coal-fired micro-CHP system coupled engine as a domestic solution," Energy, Elsevier, vol. 274(C).
    10. Tumen Ozdil, N. Filiz & Tantekin, Atakan, 2016. "Exergy and exergoeconomic assessments of an electricity production system in a running wastewater treatment plant," Renewable Energy, Elsevier, vol. 97(C), pages 390-398.
    11. Powell, Kody M. & Rashid, Khalid & Ellingwood, Kevin & Tuttle, Jake & Iverson, Brian D., 2017. "Hybrid concentrated solar thermal power systems: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 215-237.
    12. Sylwia Myszograj & Dariusz Bocheński & Mirosław Mąkowski & Ewelina Płuciennik-Koropczuk, 2021. "Biogas, Solar and Geothermal Energy—The Way to a Net-Zero Energy Wastewater Treatment Plant—A Case Study," Energies, MDPI, vol. 14(21), pages 1-15, October.
    13. Ghaebi, Hadi & Yari, Mortaza & Gargari, Saeed Ghavami & Rostamzadeh, Hadi, 2019. "Thermodynamic modeling and optimization of a combined biogas steam reforming system and organic Rankine cycle for coproduction of power and hydrogen," Renewable Energy, Elsevier, vol. 130(C), pages 87-102.
    14. Abbas, Tahir & Ali, Ghaffar & Adil, Sultan Ali & Bashir, Muhammad Khalid & Kamran, Muhammad Asif, 2017. "Economic analysis of biogas adoption technology by rural farmers: The case of Faisalabad district in Pakistan," Renewable Energy, Elsevier, vol. 107(C), pages 431-439.
    15. Soleymani, Elahe & Ghaebi, Hadi & Heydari, Amir & Javani, Nader, 2024. "Thermodynamic analysis and examining the effects of parameters in BSR-HDH system using response surface methodology," Renewable Energy, Elsevier, vol. 226(C).
    16. de Souza, Celso Correia & Leandro, José Paulo & dos Reis Neto, José Francisco & Frainer, Daniel Massen & Castelão, Raul Assef, 2018. "Cogeneration of electricity in sugar-alcohol plant: Perspectives and viability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 832-837.
    17. Ren, Fukang & Wei, Ziqing & Zhai, Xiaoqiang, 2022. "A review on the integration and optimization of distributed energy systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 162(C).
    18. Guo, Shaopeng & Liu, Qibin & Sun, Jie & Jin, Hongguang, 2018. "A review on the utilization of hybrid renewable energy," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 1121-1147.
    19. Shane, Agabu & Gheewala, Shabbir H. & Kafwembe, Young, 2017. "Urban commercial biogas power plant model for Zambian towns," Renewable Energy, Elsevier, vol. 103(C), pages 1-14.
    20. Sarker, Swati Anindita & Wang, Shouyang & Adnan, K.M. Mehedi & Sattar, M. Nahid, 2020. "Economic feasibility and determinants of biogas technology adoption: Evidence from Bangladesh," Renewable and Sustainable Energy Reviews, Elsevier, vol. 123(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:109:y:2017:i:c:p:188-194. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.