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Pretreatment of oil palm trunk in deep eutectic solvent and optimization of enzymatic hydrolysis of pretreated oil palm trunk

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  • Zulkefli, Syarilaida
  • Abdulmalek, Emilia
  • Abdul Rahman, Mohd. Basyaruddin

Abstract

Deep eutectic solvents (DES) were utilised as pretreatment media on oil palm trunk (OPT) fibre in order to change the morphology of the highly crystalline cellulose prior to enzymatic hydrolysis. Among all the DESs tested, ethylammonium chloride: ethylene glycol (EAC:EG) was found to be the most efficient solvent for the pretreatment of OPT fibre. The pretreatment of OPT by EAC:EG had removed 42% lignin and 83% hemicellulose with the ability to dissolve the OPT biomass (58%) after heating at 100 °C for 48 h. FTIR analysis was used in determining the chemical characteristic changes where OPT treated in EAC:EG had more disruption of hydroxyl bond and indication of delignification compared to OPT treated with other DESs. Enzymatic hydrolysis was carried out on OPT treated in EAC:EG and the highest glucose production (74%) was achieved at 50 °C after 24 h with 15 mg/mL substrate concentration, 50 FPU/g of Celluclast 1.5 L and 100 CBU/ml of Novozyme 188.

Suggested Citation

  • Zulkefli, Syarilaida & Abdulmalek, Emilia & Abdul Rahman, Mohd. Basyaruddin, 2017. "Pretreatment of oil palm trunk in deep eutectic solvent and optimization of enzymatic hydrolysis of pretreated oil palm trunk," Renewable Energy, Elsevier, vol. 107(C), pages 36-41.
    • Handle: RePEc:eee:renene:v:107:y:2017:i:c:p:36-41
    DOI: 10.1016/j.renene.2017.01.037
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    References listed on IDEAS

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    1. Tan, Kok Tat & Lee, Keat Teong & Mohamed, Abdul Rahman, 2008. "Role of energy policy in renewable energy accomplishment: The case of second-generation bioethanol," Energy Policy, Elsevier, vol. 36(9), pages 3360-3365, September.
    2. Shuit, S.H. & Tan, K.T. & Lee, K.T. & Kamaruddin, A.H., 2009. "Oil palm biomass as a sustainable energy source: A Malaysian case study," Energy, Elsevier, vol. 34(9), pages 1225-1235.
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    1. Tnah, Shen Khang & Wu, Ta Yeong & Ting, Dennis Chiong Chung & Chow, Han Ket & Shak, Katrina Pui Yee & Subramonian, Wennie & Procentese, Alessandra & Cheng, Chin Kui & Teoh, Wen Hui & Md. Jahim, Jamali, 2022. "Effect of chlorine atoms in choline chloride-monocarboxylic acid for the pretreatment of oil palm fronds and enzymatic hydrolysis," Renewable Energy, Elsevier, vol. 182(C), pages 285-295.
    2. Liu, Yao & Zheng, Xiaojie & Tao, Shunhui & Hu, Lei & Zhang, Xiaodong & Lin, Xiaoqing, 2021. "Process optimization for deep eutectic solvent pretreatment and enzymatic hydrolysis of sugar cane bagasse for cellulosic ethanol fermentation," Renewable Energy, Elsevier, vol. 177(C), pages 259-267.
    3. Intan Nazirah Mohammad & Clarence M. Ongkudon & Mailin Misson, 2020. "Physicochemical Properties and Lignin Degradation of Thermal-Pretreated Oil Palm Empty Fruit Bunch," Energies, MDPI, vol. 13(22), pages 1-12, November.
    4. Yang, Luan & Zheng, Tianran & Huang, Chen & Yao, Jianfeng, 2022. "Using deep eutectic solvent pretreatment for enhanced enzymatic saccharification and lignin utilization of masson pine," Renewable Energy, Elsevier, vol. 195(C), pages 681-687.

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