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Triplet interactions and the c(2×2) overlayer phase diagram

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  • Ceder, G.
  • Dreyssé, H.
  • de Fontaine, D.

Abstract

Square lattice phase diagrams are investigated with the extended Ising model, considering pair and triplet interactions. We determine the stability of the c(2×2) structure as a function of different triplet interactions. A systematical study of the asymmetry of the phase diagram shows that the triplet interactions with two nnn bounds play a major role in producing an asymmetric phase diagram. The experimental phase diagram of hydrogen adsorbed on a Pd (001) surface is discussed within this framework.

Suggested Citation

  • Ceder, G. & Dreyssé, H. & de Fontaine, D., 1993. "Triplet interactions and the c(2×2) overlayer phase diagram," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 193(1), pages 105-113.
    • Handle: RePEc:eee:phsmap:v:193:y:1993:i:1:p:105-113
    DOI: 10.1016/0378-4371(93)90217-R
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