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Molecular dynamical calculations on the transport properties of a square-well fluid

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  • Michels, J.P.J.
  • Trappeniers, N.J.

Abstract

The coefficient of viscosity for a system consisting of square-well molecules has been determined, by means of computer simulation, in a density region ranging from the critical up to densities which are just below the fluid-solid phase transition. The inclusion of an attractive part in the intermolecular potential has a profound influence on the viscosity, and is also responsible for an improvement in the correspondence with experimental evidence. A comparison with the Davis-Rice-Sengers (DRS) theory shows that the applicability of the latter is restricted.

Suggested Citation

  • Michels, J.P.J. & Trappeniers, N.J., 1980. "Molecular dynamical calculations on the transport properties of a square-well fluid," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 104(1), pages 243-254.
    • Handle: RePEc:eee:phsmap:v:104:y:1980:i:1:p:243-254
    DOI: 10.1016/0378-4371(80)90085-0
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    References listed on IDEAS

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    1. T. Collings & C. Stoneman, 1976. "The M / M /∞ Queue with Varying Arrival and Departure Rates," Operations Research, INFORMS, vol. 24(4), pages 760-773, August.
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