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Thermocatalytic pyrolysis of Sesbania bispinosa biomass over Y-zeolite catalyst towards clean fuel and valuable chemicals

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  • Nawaz, Ahmad
  • Kumar, Pradeep

Abstract

The thermocatalytic pyrolysis of Sesbania bispinosa (SB) biomass was performed in a cylindrical-shaped pyrolyzer to produce renewable fuel and chemicals. The important process parameters, such as temperature, heating rate, and N2 flow rate, were optimized using the response surface methodology (RSM). Pyrolysis of the SB biomass was also performed at different catalyst to biomass ratios (C/B) (1:3, 1:6, 1:9, and 1:12). The pyrolysis findings indicated that normal pyrolysis produced a greater yield of bio-oil (42.53 wt %) than catalytic pyrolysis (40.71 wt %) that obtained at 1:9 C/B ratio. The use of catalyst reduced the yield of bio-oil; however, fuel characteristics get enhanced. FTIR analysis of normal and catalytic bio-oil verified the existence of different functional groups, whereas GCMS result at optimized pyrolysis condition confirmed increased hydrocarbons in the catalytic bio-oil. Further, the characterization result of the biochar revealed its potential for use in a variety of industrial and agricultural applications.

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  • Nawaz, Ahmad & Kumar, Pradeep, 2023. "Thermocatalytic pyrolysis of Sesbania bispinosa biomass over Y-zeolite catalyst towards clean fuel and valuable chemicals," Energy, Elsevier, vol. 263(PB).
    • Handle: RePEc:eee:energy:v:263:y:2023:i:pb:s0360544222025701
    DOI: 10.1016/j.energy.2022.125684
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    References listed on IDEAS

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    1. Wang, Kaige & Zhang, Jing & Shanks, Brent H. & Brown, Robert C., 2015. "The deleterious effect of inorganic salts on hydrocarbon yields from catalytic pyrolysis of lignocellulosic biomass and its mitigation," Applied Energy, Elsevier, vol. 148(C), pages 115-120.
    2. Nawaz, Ahmad & Kumar, Pradeep, 2022. "Elucidating the bioenergy potential of raw, hydrothermally carbonized and torrefied waste Arundo donax biomass in terms of physicochemical characterization, kinetic and thermodynamic parameters," Renewable Energy, Elsevier, vol. 187(C), pages 844-856.
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    2. Nawaz, Ahmad & Razzak, Shaikh Abdur, 2024. "Co-pyrolysis of biomass and different plastic waste to reduce hazardous waste and subsequent production of energy products: A review on advancement, synergies, and future prospects," Renewable Energy, Elsevier, vol. 224(C).
    3. Qin, Kang & Ye, Sishi & Wu, Le, 2024. "Process design and analysis of a net-zero carbon emissions hydrocracking unit integrating co-processing technique with green hydrogen and electricity," Energy, Elsevier, vol. 295(C).
    4. Yu, Zhang & Ahmad, Muhammad Sajjad & Shen, Boxiong & Li, Yingna & Ibrahim, Muhammad & Bokhari, Awais & Klemeš, Jiří Jaromír, 2023. "Activated waste cotton cellulose as renewable fuel and value-added chemicals: Thermokinetic analysis, coupled pyrolysis with gas chromatography and mass spectrometry," Energy, Elsevier, vol. 283(C).

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