IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v181y2019icp136-147.html
   My bibliography  Save this article

Correlation analysis of the functional groups and exothermic characteristics of bituminous coal molecules during high-temperature oxidation

Author

Listed:
  • Zhao, Jingyu
  • Deng, Jun
  • Chen, Long
  • Wang, Tao
  • Song, Jiajia
  • Zhang, Yanni
  • Shu, Chi-Min
  • Zeng, Qiang

Abstract

Coal spontaneous combustion is characterized by high-temperature oxidation and microscopic mechanisms. These are essential aspects to understand when attempting to control or prevent spontaneous combustion. Three fresh bituminous coal samples were collected for experimentation from Huainan, China. X-ray diffraction and Fourier-transform infrared spectrometry were conducted to determine the microscopic characteristics of coal during high-temperature oxidation. The mineral structures and functional groups were ascertained to ensure that the original structural characteristics of the coals were obtained. Thermogravimetry–differential scanning calorimetry was used to divide the high-temperature oxidation into four substages and obtain detailed exothermic characteristics. The heat energy release exhibited a positive correlation with an increase in temperature.

Suggested Citation

  • Zhao, Jingyu & Deng, Jun & Chen, Long & Wang, Tao & Song, Jiajia & Zhang, Yanni & Shu, Chi-Min & Zeng, Qiang, 2019. "Correlation analysis of the functional groups and exothermic characteristics of bituminous coal molecules during high-temperature oxidation," Energy, Elsevier, vol. 181(C), pages 136-147.
    • Handle: RePEc:eee:energy:v:181:y:2019:i:c:p:136-147
    DOI: 10.1016/j.energy.2019.05.158
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544219310400
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2019.05.158?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Wang, Chang'an & Wu, Song & Lv, Qiang & Liu, Xuan & Chen, Wufeng & Che, Defu, 2017. "Study on correlations of coal chemical properties based on database of real-time data," Applied Energy, Elsevier, vol. 204(C), pages 1115-1123.
    2. Lin, Xiongchao & Luo, Meng & Li, Shouyi & Yang, Yuanping & Chen, Xujun & Tian, Bin & Wang, Yonggang, 2017. "The evolutionary route of coal matrix during integrated cascade pyrolysis of a typical low-rank coal," Applied Energy, Elsevier, vol. 199(C), pages 335-346.
    3. Zhang, Jie & Zheng, Nan & Wang, Jie, 2016. "Two-stage hydrogasification of different rank coals with a focus on relationships between yields of products and coal properties or structures," Applied Energy, Elsevier, vol. 173(C), pages 438-447.
    4. Deng, Jun & Yang, Yi & Zhang, Yan-Ni & Liu, Bo & Shu, Chi-Min, 2018. "Inhibiting effects of three commercial inhibitors in spontaneous coal combustion," Energy, Elsevier, vol. 160(C), pages 1174-1185.
    5. Duan, Feng & Chyang, Chien-Song & Zhang, Li-hui & Chi, Yi-Ting, 2015. "Effect of the molecular structure of nitrogen compounds on the pollutant formation in a bubbling fluidized-bed combustor," Energy, Elsevier, vol. 83(C), pages 394-402.
    6. Phiri, Zebron & Everson, Raymond C. & Neomagus, Hein W.J.P. & Wood, Barry J., 2018. "Transformation of nitrogen functional forms and the accompanying chemical-structural properties emanating from pyrolysis of bituminous coals," Applied Energy, Elsevier, vol. 216(C), pages 414-427.
    7. Xu, Jun & Tang, Hao & Su, Sheng & Liu, Jiawei & Xu, Kai & Qian, Kun & Wang, Yi & Zhou, Yingbiao & Hu, Song & Zhang, Anchao & Xiang, Jun, 2018. "A study of the relationships between coal structures and combustion characteristics: The insights from micro-Raman spectroscopy based on 32 kinds of Chinese coals," Applied Energy, Elsevier, vol. 212(C), pages 46-56.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Lü, Hui-Fei & Deng, Jun & Li, Da-Jiang & Xu, Fan & Xiao, Yang & Shu, Chi-Min, 2021. "Effect of oxidation temperature and oxygen concentration on macro characteristics of pre-oxidised coal spontaneous combustion process," Energy, Elsevier, vol. 227(C).
    2. Xu, Jun & Tang, Hao & Su, Sheng & Liu, Jiawei & Xu, Kai & Qian, Kun & Wang, Yi & Zhou, Yingbiao & Hu, Song & Zhang, Anchao & Xiang, Jun, 2018. "A study of the relationships between coal structures and combustion characteristics: The insights from micro-Raman spectroscopy based on 32 kinds of Chinese coals," Applied Energy, Elsevier, vol. 212(C), pages 46-56.
    3. Li, Hongjun & Chang, Qinghua & Gao, Rui & Dai, Zhenghua & Chen, Xueli & Yu, Guangsuo & Wang, Fuchen, 2018. "Fractal characteristics and reactivity evolution of lignite during the upgrading process by supercritical CO2 extraction," Applied Energy, Elsevier, vol. 225(C), pages 559-569.
    4. Yang Ma & Yan Gao & Xiumin Jiang, 2023. "Influences of the Introduced O-Containing Functional Groups on the Gaseous Pyrolysis Product of Superfine Pulverized Coal," Energies, MDPI, vol. 16(11), pages 1-17, May.
    5. Yan, Hongwei & Nie, Baisheng & Kong, Fanbei & Liu, Yuze & Liu, Peijun & Wang, Yongjing & Chen, Zongyu & Yin, Feifei & Gong, Jie & Lin, Shuangshuang & Wang, Xiaotong & Hou, Yanan, 2023. "Experimental investigation of coal particle size on the kinetic properties of coal oxidation and spontaneous combustion limit parameters," Energy, Elsevier, vol. 270(C).
    6. Barbara Bielowicz & Rafał Morga, 2021. "Micro-Raman Spectroscopy of Selected Macerals of the Huminite Group: An Example from the Szczerców Lignite Deposit (Central Poland)," Energies, MDPI, vol. 14(2), pages 1-18, January.
    7. Li, Jiawei & Fan, Subo & Zhang, Xuyang & Chen, Zhichao & Qiao, Yanyu & Yuan, Zhenhua & Zeng, Lingyan & Li, Zhengqi, 2022. "Physicochemical structure, combustion characteristics and SiO2 properties of entrained flow gasification ash," Energy, Elsevier, vol. 251(C).
    8. Jiang, Xu & Xu, Jun & He, Qichen & Wang, Cong & Jiang, Long & Xu, Kai & Wang, Yi & Su, Sheng & Hu, Song & Du, Zhenyi & Xiang, Jun, 2023. "A study of the relationships between coal heterogeneous chemical structure and pyrolysis behaviours: Mechanism and predicting model," Energy, Elsevier, vol. 282(C).
    9. Li, Jinhu & Li, Zenghua & Yang, Yongliang & Duan, Yujian & Xu, Jun & Gao, Ruiting, 2019. "Examination of CO, CO2 and active sites formation during isothermal pyrolysis of coal at low temperatures," Energy, Elsevier, vol. 185(C), pages 28-38.
    10. Lu, Wei & Gao, Ao & Sun, Weili & Liang, Yuntao & He, Zhenglong & Li, Jinliang & Sun, Yong & Song, Shuanglin & Meng, Shaocong & Cao, Yingjiazi, 2022. "Experimental study on inhibition of spontaneous combustion of different-rank coals by high-performance m-Cresol water-based inhibitor solutions," Energy, Elsevier, vol. 261(PA).
    11. Zhai, Xiaowei & Ge, Hui & Wang, Tingyan & Shu, Chi-Min & Li, Jun, 2020. "Effect of water immersion on active functional groups and characteristic temperatures of bituminous coal," Energy, Elsevier, vol. 205(C).
    12. Chen, Zhaohui & Li, Yunjia & Lai, Dengguo & Geng, Sulong & Zhou, Qi & Gao, Shiqiu & Xu, Guangwen, 2018. "Coupling coal pyrolysis with char gasification in a multi-stage fluidized bed to co-produce high-quality tar and syngas," Applied Energy, Elsevier, vol. 215(C), pages 348-355.
    13. Zhu, Shujun & Hui, Jicheng & Lyu, Qinggang & Ouyang, Ziqu & Zeng, Xiongwei & Zhu, Jianguo & Liu, Jingzhang & Cao, Xiaoyang & Zhang, Xiaoyu & Ding, Hongliang & Liu, Yuhua, 2023. "Experimental study on pulverized coal swirl-opposed combustion preheated by a circulating fluidized bed. Part A. Wide-load operation and low-NOx emission characteristics," Energy, Elsevier, vol. 284(C).
    14. Wang, Pengqian & Wang, Chang'an & Yuan, Maobo & Wang, Chaowei & Zhang, Jinping & Du, Yongbo & Tao, Zichen & Che, Defu, 2020. "Experimental evaluation on co-combustion characteristics of semi-coke and coal under enhanced high-temperature and strong-reducing atmosphere," Applied Energy, Elsevier, vol. 260(C).
    15. Qiao, Yanyu & Chen, Zhichao & Wu, Xiaolan & Li, Zhengqi, 2023. "Effect of demineralization on waste tire pyrolysis char physical, chemical characteristics and combustion characteristics," Energy, Elsevier, vol. 284(C).
    16. Ma, Cheng & Zhao, Yuzhen & Lang, Tingting & Zou, Chong & Zhao, Junxue & Miao, Zongcheng, 2023. "Pyrolysis characteristics of low-rank coal in a low-nitrogen pyrolysis atmosphere and properties of the prepared chars," Energy, Elsevier, vol. 277(C).
    17. Li, Min & Yang, Xueqin & Lu, Yi & Wang, Deming & Shi, Shiliang & Ye, Qing & Li, He & Wang, Zheng, 2023. "Thermodynamic variation law and influence mechanism of low-temperature oxidation of lignite samples with different moisture contents," Energy, Elsevier, vol. 262(PB).
    18. Zhou, Chunbao & Chen, Yuanxiang & Xing, Xuyang & Chen, Lei & Liu, Chenglong & Chao, Li & Yao, Bang & Zhang, Yingwen & Dai, Jianjun & Liu, Yang & Wang, Jun & Dong, Jie & Li, Yunxiang & Fan, Dekai & Wan, 2024. "Pilot-scale pyrolysis and activation of typical biomass chips in an interconnected dual fluidized bed: Comparison and analysis of products," Renewable Energy, Elsevier, vol. 225(C).
    19. Guo, Shengli & Yan, Zhuo & Yuan, Shujie & Weile Geng,, 2021. "Inhibitory effect and mechanism of l-ascorbic acid combined with tea polyphenols on coal spontaneous combustion," Energy, Elsevier, vol. 229(C).
    20. Buxin Su & Guangwei Wang & Renguo Li & Kun Xu & Junyi Wu & Desheng Li & Jiawen Liu, 2022. "Co-Combustion Behavior of Paper Sludge Hydrochar and Pulverized Coal: Low Rank Coal and Its Product by Hydrothermal Carbonization," Energies, MDPI, vol. 15(15), pages 1-12, August.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:181:y:2019:i:c:p:136-147. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.