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Development of a modified equilibrium model for biomass pilot-scale fluidized bed gasifier performance predictions

Author

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  • Rodriguez-Alejandro, David A.
  • Nam, Hyungseok
  • Maglinao, Amado L.
  • Capareda, Sergio C.
  • Aguilera-Alvarado, Alberto F.

Abstract

The objective of this work is to develop a thermodynamic model considering non-stoichiometric restrictions. The model validation was done from experimental works using a bench-scale fluidized bed gasifier with wood chips, dairy manure, and sorghum. The model was used for a further parametric study to predict the performance of a pilot-scale fluidized biomass gasifier. The Gibbs free energy minimization was applied to the modified equilibrium model considering a heat loss to the surroundings, carbon efficiency, and two non-equilibrium factors based on empirical correlations of ER and gasification temperature. The model was in a good agreement with RMS <4 for the produced gas. The parametric study ranges were 0.01 < ER < 0.99 and 500 °C < T < 900 °C to predict syngas concentrations and its LHV (lower heating value) for the optimization. Higher aromatics in tar were contained in WC gasification compared to manure gasification. A wood gasification tar simulation was produced to predict the amount of tars at specific conditions. The operating conditions for the highest quality syngas were reconciled experimentally with three biomass wastes using a fluidized bed gasifier. The thermodynamic model was used to predict the gasification performance at conditions beyond the actual operation.

Suggested Citation

  • Rodriguez-Alejandro, David A. & Nam, Hyungseok & Maglinao, Amado L. & Capareda, Sergio C. & Aguilera-Alvarado, Alberto F., 2016. "Development of a modified equilibrium model for biomass pilot-scale fluidized bed gasifier performance predictions," Energy, Elsevier, vol. 115(P1), pages 1092-1108.
    • Handle: RePEc:eee:energy:v:115:y:2016:i:p1:p:1092-1108
    DOI: 10.1016/j.energy.2016.09.079
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    5. Qiu, Jianhua & Wu, Fujun & Chen, Fangzhou & Huang, Weijia & Cai, Yezheng & Jiang, Juantao, 2022. "Entire process simulation and thermodynamic analysis of the catalytic gasification for synthetic natural gas from biomass," Energy, Elsevier, vol. 255(C).
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    7. Pio, D.T. & Tarelho, L.A.C., 2020. "Empirical and chemical equilibrium modelling for prediction of biomass gasification products in bubbling fluidized beds," Energy, Elsevier, vol. 202(C).
    8. Silva, Isabelly P. & Lima, Rafael M.A. & Santana, Hortência E.P. & Silva, Gabriel F. & Ruzene, Denise S. & Silva, Daniel P., 2022. "Development of a semi-empirical model for woody biomass gasification based on stoichiometric thermodynamic equilibrium model," Energy, Elsevier, vol. 241(C).
    9. Porcu, Andrea & Xu, Yupeng & Mureddu, Mauro & Dessì, Federica & Shahnam, Mehrdad & Rogers, William A. & Sastri, Bhima S. & Pettinau, Alberto, 2021. "Experimental validation of a multiphase flow model of a lab-scale fluidized-bed gasification unit," Applied Energy, Elsevier, vol. 293(C).
    10. Qatan, Hesham Sadeq Obaid & Wan Ab Karim Ghani, Wan Azlina & Md Said, Mohamad Syazarudin, 2023. "Prediction and optimization of syngas production from Napier grass air gasification via kinetic modelling and response surface methodology," Energy, Elsevier, vol. 270(C).

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