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Effect of iron promoter on structure and performance of CuMnZnO catalyst for higher alcohols synthesis

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  • Ding, Mingyue
  • Qiu, Minghuang
  • Wang, Tiejun
  • Ma, Longlong
  • Wu, Chuangzhi
  • Liu, Jianguo

Abstract

Effect of iron promoter on the microstructures of CuMnZnO catalysts was investigated by N2 physical adsorption (BET), X-ray diffraction (XRD), and temperature-programmed reduction of hydrogen (H2-TPR). Higher alcohols synthesis (HAS) was performed in a fixed bed reactor. The characterization results indicated that incorporation of iron in the CuMnZnO catalyst resulted in the increase of BET surface area and the dispersion of catalyst particles. Adding iron facilitated the formation of Fe–Mn solid solution and reduced the interaction between copper and manganese, which promoted the separation of CuO from the Cu–Mn solid solution and the reduction of the catalyst. In the HAS reaction, the catalytic activity of CO hydrogenation and the selectivity to C2+OH and hydrocarbons presented an increasing trend with the increase in iron concentration, which may be attributed to the synergistic effect between the dispersed copper and iron carbides.

Suggested Citation

  • Ding, Mingyue & Qiu, Minghuang & Wang, Tiejun & Ma, Longlong & Wu, Chuangzhi & Liu, Jianguo, 2012. "Effect of iron promoter on structure and performance of CuMnZnO catalyst for higher alcohols synthesis," Applied Energy, Elsevier, vol. 97(C), pages 543-547.
    • Handle: RePEc:eee:appene:v:97:y:2012:i:c:p:543-547
    DOI: 10.1016/j.apenergy.2011.11.083
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    References listed on IDEAS

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    1. Hammond, G.P. & Kallu, S. & McManus, M.C., 2008. "Development of biofuels for the UK automotive market," Applied Energy, Elsevier, vol. 85(6), pages 506-515, June.
    2. Fatih Demirbas, M., 2009. "Biorefineries for biofuel upgrading: A critical review," Applied Energy, Elsevier, vol. 86(Supplemen), pages 151-161, November.
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    Cited by:

    1. Kim, Young-Doo & Yang, Chang-Won & Kim, Beom-Jong & Moon, Ji-Hong & Jeong, Jae-Yong & Jeong, Soo-Hwa & Lee, See-Hoon & Kim, Jae-Ho & Seo, Myung-Won & Lee, Sang-Bong & Kim, Jae-Kon & Lee, Uen-Do, 2016. "Fischer–tropsch diesel production and evaluation as alternative automotive fuel in pilot-scale integrated biomass-to-liquid process," Applied Energy, Elsevier, vol. 180(C), pages 301-312.
    2. Ding, Mingyue & Yang, Yong & Li, Yongwang & Wang, Tiejun & Ma, Longlong & Wu, Chuangzhi, 2013. "Impact of H2/CO ratios on phase and performance of Mn-modified Fe-based Fischer Tropsch synthesis catalyst," Applied Energy, Elsevier, vol. 112(C), pages 1241-1246.
    3. Ding, Mingyue & Tu, Junling & Qiu, Minghuang & Wang, Tiejun & Ma, Longlong & Li, Yuping, 2015. "Impact of potassium promoter on Cu–Fe based mixed alcohols synthesis catalyst," Applied Energy, Elsevier, vol. 138(C), pages 584-589.

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