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The effect of elevated temperature on the accelerated aging of LiCoO2/mesocarbon microbeads batteries

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  • Guan, Ting
  • Sun, Shun
  • Gao, Yunzhi
  • Du, Chunyu
  • Zuo, Pengjian
  • Cui, Yingzhi
  • Zhang, Lingling
  • Yin, Geping

Abstract

This work studies the aging processes of commercial LiCoO2/mesocarbon microbeads (MCMB) cells which are cycled at 25°C, 35°C, 45°C respectively at the 0.6C charge/discharge rate and 30% depth of discharge. The capacity degradation of the cells is fast at elevated temperature, and the cycle life tested at 45°C is about a quarter of the cycling time at 25°C. The fresh and the aged cells are disassembled to characterize the morphology and the composition of electrode surface, as well as the bulk structure and the electrochemical performance of single electrode. It is found that the formation of SEI film and the polarization of the full cell lead to state of charge (SOC) shift in the cathode. The cathode SOC shift and the decay in the reversible capacity of LiCoO2 cathode dominate the aging of the full cell. The former is the prevailing aging factor at 25°C, while the latter factor becomes the leading cause of cell aging at 45°C. The unstable and thick SEI film on the cathode under elevated temperature influences the lithium ion diffusion, resulting in the increased polarization and the decreased intrinsic performance of LiCoO2 cathode. The proper range of test temperature ensuring no changes in aging mechanism and the decay rate of capacity caused by each aging factor are proposed by analyzing the performance of the full cells and the electrodes. After comparing the test results, it is concluded that the aging process at 45°C is not the same as that at room temperature.

Suggested Citation

  • Guan, Ting & Sun, Shun & Gao, Yunzhi & Du, Chunyu & Zuo, Pengjian & Cui, Yingzhi & Zhang, Lingling & Yin, Geping, 2016. "The effect of elevated temperature on the accelerated aging of LiCoO2/mesocarbon microbeads batteries," Applied Energy, Elsevier, vol. 177(C), pages 1-10.
    • Handle: RePEc:eee:appene:v:177:y:2016:i:c:p:1-10
    DOI: 10.1016/j.apenergy.2016.05.101
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    1. Jalkanen, K. & Karppinen, J. & Skogström, L. & Laurila, T. & Nisula, M. & Vuorilehto, K., 2015. "Cycle aging of commercial NMC/graphite pouch cells at different temperatures," Applied Energy, Elsevier, vol. 154(C), pages 160-172.
    2. Omar, Noshin & Monem, Mohamed Abdel & Firouz, Yousef & Salminen, Justin & Smekens, Jelle & Hegazy, Omar & Gaulous, Hamid & Mulder, Grietus & Van den Bossche, Peter & Coosemans, Thierry & Van Mierlo, J, 2014. "Lithium iron phosphate based battery – Assessment of the aging parameters and development of cycle life model," Applied Energy, Elsevier, vol. 113(C), pages 1575-1585.
    3. Zhao, Rui & Liu, Jie & Gu, Junjie, 2015. "The effects of electrode thickness on the electrochemical and thermal characteristics of lithium ion battery," Applied Energy, Elsevier, vol. 139(C), pages 220-229.
    4. Sarasketa-Zabala, E. & Martinez-Laserna, E. & Berecibar, M. & Gandiaga, I. & Rodriguez-Martinez, L.M. & Villarreal, I., 2016. "Realistic lifetime prediction approach for Li-ion batteries," Applied Energy, Elsevier, vol. 162(C), pages 839-852.
    5. Waag, Wladislaw & Käbitz, Stefan & Sauer, Dirk Uwe, 2013. "Experimental investigation of the lithium-ion battery impedance characteristic at various conditions and aging states and its influence on the application," Applied Energy, Elsevier, vol. 102(C), pages 885-897.
    6. Su, Laisuo & Zhang, Jianbo & Wang, Caijuan & Zhang, Yakun & Li, Zhe & Song, Yang & Jin, Ting & Ma, Zhao, 2016. "Identifying main factors of capacity fading in lithium ion cells using orthogonal design of experiments," Applied Energy, Elsevier, vol. 163(C), pages 201-210.
    7. Abdel Monem, Mohamed & Trad, Khiem & Omar, Noshin & Hegazy, Omar & Mantels, Bart & Mulder, Grietus & Van den Bossche, Peter & Van Mierlo, Joeri, 2015. "Lithium-ion batteries: Evaluation study of different charging methodologies based on aging process," Applied Energy, Elsevier, vol. 152(C), pages 143-155.
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    2. Li, Hao & Zhang, Weige & Sun, Bingxiang & Cai, Xue & Fan, Xinyuan & Zhao, Bo & Zhang, Caiping, 2023. "The degradation characteristics and mechanism of Li[Ni0.5Co0.2Mn0.3]O2 batteries with high frequency current ripple excitation," Applied Energy, Elsevier, vol. 343(C).
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