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New highly efficient regeneration process for thermochemical energy storage

Author

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  • Mette, Barbara
  • Kerskes, Henner
  • Drück, Harald
  • Müller-Steinhagen, Hans

Abstract

Thermochemical energy storage is a key technology to realize highly efficient thermal energy storages for various applications such as solar thermal systems or cogeneration systems. As thermal storage material zeolite and composite materials of zeolite and e.g. salts are the subject of intensive research at present. These materials meet the combined requirements of high energy storage density and good heat transfer rates. However, in order to obtain a high energy storage density, comparatively high temperatures of in excess of 180°C are needed during the regeneration process. This is a drawback especially when used as storage material in solar thermal systems. In this paper, a new regeneration strategy is proposed for an open sorption process. The new regeneration strategy allows regeneration of the storage material at significantly lower temperatures without reducing the energy storage density of the material. For the example of a solar thermal combisystem with thermochemical energy storage, a concept for integrating this new regeneration strategy into an overall system will be presented. For an energetic assessment, annual system simulations have been performed with the dynamic simulation software TRNSYS. A comparison of the system design with a “conventional” regeneration strategy (regeneration temperature of 180°C) and with the new regeneration strategy (regeneration temperature of 130°C) has been made. The results of the simulation study show that with the new regeneration strategy the fractional energy saving as a measure of the thermal performance of the system can be maintained or even increased. These promising results demonstrate that this process design may be a breakthrough in realizing thermochemical energy storages for solar thermal applications based on high performance zeolite or zeolite composite materials.

Suggested Citation

  • Mette, Barbara & Kerskes, Henner & Drück, Harald & Müller-Steinhagen, Hans, 2013. "New highly efficient regeneration process for thermochemical energy storage," Applied Energy, Elsevier, vol. 109(C), pages 352-359.
    • Handle: RePEc:eee:appene:v:109:y:2013:i:c:p:352-359
    DOI: 10.1016/j.apenergy.2013.01.087
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    Cited by:

    1. Aydin, Devrim & Casey, Sean P. & Chen, Xiangjie & Riffat, Saffa, 2018. "Numerical and experimental analysis of a novel heat pump driven sorption storage heater," Applied Energy, Elsevier, vol. 211(C), pages 954-974.
    2. Lehmann, Christoph & Beckert, Steffen & Nonnen, Thomas & Gläser, Roger & Kolditz, Olaf & Nagel, Thomas, 2017. "Water loading lift and heat storage density prediction of adsorption heat storage systems using Dubinin-Polanyi theory—Comparison with experimental results," Applied Energy, Elsevier, vol. 207(C), pages 274-282.
    3. Nagel, Thomas & Beckert, Steffen & Lehmann, Christoph & Gläser, Roger & Kolditz, Olaf, 2016. "Multi-physical continuum models of thermochemical heat storage and transformation in porous media and powder beds—A review," Applied Energy, Elsevier, vol. 178(C), pages 323-345.
    4. Lehmann, Christoph & Beckert, Steffen & Gläser, Roger & Kolditz, Olaf & Nagel, Thomas, 2017. "Assessment of adsorbate density models for numerical simulations of zeolite-based heat storage applications," Applied Energy, Elsevier, vol. 185(P2), pages 1965-1970.
    5. Li, T.X. & Wu, S. & Yan, T. & Xu, J.X. & Wang, R.Z., 2016. "A novel solid–gas thermochemical multilevel sorption thermal battery for cascaded solar thermal energy storage," Applied Energy, Elsevier, vol. 161(C), pages 1-10.
    6. Finck, Christian & Li, Rongling & Kramer, Rick & Zeiler, Wim, 2018. "Quantifying demand flexibility of power-to-heat and thermal energy storage in the control of building heating systems," Applied Energy, Elsevier, vol. 209(C), pages 409-425.
    7. Kong, Hui & Hao, Yong & Jin, Hongguang, 2018. "Isothermal versus two-temperature solar thermochemical fuel synthesis: A comparative study," Applied Energy, Elsevier, vol. 228(C), pages 301-308.
    8. Kuznik, Frédéric & Gondre, Damien & Johannes, Kévyn & Obrecht, Christian & David, Damien, 2019. "Numerical modelling and investigations on a full-scale zeolite 13X open heat storage for buildings," Renewable Energy, Elsevier, vol. 132(C), pages 761-772.
    9. Johannes, Kévyn & Kuznik, Frédéric & Hubert, Jean-Luc & Durier, Francois & Obrecht, Christian, 2015. "Design and characterisation of a high powered energy dense zeolite thermal energy storage system for buildings," Applied Energy, Elsevier, vol. 159(C), pages 80-86.
    10. Nagel, T. & Shao, H. & Roßkopf, C. & Linder, M. & Wörner, A. & Kolditz, O., 2014. "The influence of gas–solid reaction kinetics in models of thermochemical heat storage under monotonic and cyclic loading," Applied Energy, Elsevier, vol. 136(C), pages 289-302.
    11. Wang, Wenqing & Kolditz, Olaf & Nagel, Thomas, 2017. "Parallel finite element modelling of multi-physical processes in thermochemical energy storage devices," Applied Energy, Elsevier, vol. 185(P2), pages 1954-1964.
    12. Michel, Benoit & Neveu, Pierre & Mazet, Nathalie, 2014. "Comparison of closed and open thermochemical processes, for long-term thermal energy storage applications," Energy, Elsevier, vol. 72(C), pages 702-716.
    13. Lizana, Jesús & Chacartegui, Ricardo & Barrios-Padura, Angela & Ortiz, Carlos, 2018. "Advanced low-carbon energy measures based on thermal energy storage in buildings: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3705-3749.
    14. Marias, Foivos & Neveu, Pierre & Tanguy, Gwennyn & Papillon, Philippe, 2014. "Thermodynamic analysis and experimental study of solid/gas reactor operating in open mode," Energy, Elsevier, vol. 66(C), pages 757-765.
    15. Jiang, Long & Gao, Jiao & Wang, Liwei & Wang, Ruzhu & Lu, Yiji & Roskilly, Anthony Paul, 2017. "Investigation on performance of multi-salt composite sorbents for multilevel sorption thermal energy storage," Applied Energy, Elsevier, vol. 190(C), pages 1029-1038.
    16. Lizana, Jesús & Chacartegui, Ricardo & Barrios-Padura, Angela & Valverde, José Manuel, 2017. "Advances in thermal energy storage materials and their applications towards zero energy buildings: A critical review," Applied Energy, Elsevier, vol. 203(C), pages 219-239.
    17. Michel, Benoit & Mazet, Nathalie & Neveu, Pierre, 2016. "Experimental investigation of an open thermochemical process operating with a hydrate salt for thermal storage of solar energy: Local reactive bed evolution," Applied Energy, Elsevier, vol. 180(C), pages 234-244.
    18. Englmair, Gerald & Moser, Christoph & Schranzhofer, Hermann & Fan, Jianhua & Furbo, Simon, 2019. "A solar combi-system utilizing stable supercooling of sodium acetate trihydrate for heat storage: Numerical performance investigation," Applied Energy, Elsevier, vol. 242(C), pages 1108-1120.
    19. Fumey, B. & Weber, R. & Baldini, L., 2019. "Sorption based long-term thermal energy storage – Process classification and analysis of performance limitations: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 111(C), pages 57-74.
    20. Englmair, Gerald & Moser, Christoph & Furbo, Simon & Dannemand, Mark & Fan, Jianhua, 2018. "Design and functionality of a segmented heat-storage prototype utilizing stable supercooling of sodium acetate trihydrate in a solar heating system," Applied Energy, Elsevier, vol. 221(C), pages 522-534.
    21. Li, Zhaojin & Bi, Yuehong & Wang, Cun & Shi, Qi & Mou, Tianhong, 2023. "Finite time thermodynamic optimization for performance of absorption energy storage systems," Energy, Elsevier, vol. 282(C).
    22. Dannemand, Mark & Dragsted, Janne & Fan, Jianhua & Johansen, Jakob Berg & Kong, Weiqiang & Furbo, Simon, 2016. "Experimental investigations on prototype heat storage units utilizing stable supercooling of sodium acetate trihydrate mixtures," Applied Energy, Elsevier, vol. 169(C), pages 72-80.
    23. Wyttenbach, Joël & Bougard, Jacques & Descy, Gilbert & Skrylnyk, Oleksandr & Courbon, Emilie & Frère, Marc & Bruyat, Fabien, 2018. "Performances and modelling of a circular moving bed thermochemical reactor for seasonal storage," Applied Energy, Elsevier, vol. 230(C), pages 803-815.
    24. Scapino, Luca & Zondag, Herbert A. & Van Bael, Johan & Diriken, Jan & Rindt, Camilo C.M., 2017. "Sorption heat storage for long-term low-temperature applications: A review on the advancements at material and prototype scale," Applied Energy, Elsevier, vol. 190(C), pages 920-948.
    25. Aydin, Devrim & Casey, Sean P. & Riffat, Saffa, 2015. "The latest advancements on thermochemical heat storage systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 356-367.

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