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Relaxtion Behavior of Elastomer Composites: The Effect of a Hybrid Carbon Black/Carbon Nanotubes Filler

Author

Listed:
  • Mansurova I. A.

    (Vyatka State University, Kirov, Russia)

  • Burkov A. A.

    (Vyatka State University, Kirov, Russia)

  • Shilov I. B.

    (Vyatka State University, Kirov, Russia)

  • Shirokova Ye. S.

    (Vyatka State University, Kirov, Russia)

  • Dolgiy E. O.

    (Vyatka State University, Kirov, Russia)

  • Khousainov A. B.

    (Kazan National Research Technological University, Kazan, Russia)

  • Belozerov V. S.

    (Vyatka State University, Kirov, Russia)

Abstract

The article analyzes relaxation α-transition in elastomeric composites containing a hybrid carbon black/carbon nanotubes (CB/CNT) filler. According to the Dynamic Mechanical Testing (DMA) data, the inclusion of hybrid particles CB/CNT in the filler leads to the expansion of the temperature dependences of the loss tangent (TanD) for all samples towards lower temperatures and the displacement of the position of the TanD maximum by a value from 4.0 up to 16 degrees in comparison with control vulcanizate. The DSC data indicate the presence of additional lowtemperature α-relaxation transitions in modified vulcanizates (-123 ... -118◦C). The observed relaxation behavior of macromolecules is due to the appearance in the material of regions with less dense packing of macromolecules and, as a consequence, the expansion of their conformational set for segmental motion under low-temperature conditions. It guarantees getting a material with increased fatigue resistance and frost resistance.

Suggested Citation

  • Mansurova I. A. & Burkov A. A. & Shilov I. B. & Shirokova Ye. S. & Dolgiy E. O. & Khousainov A. B. & Belozerov V. S., 2018. "Relaxtion Behavior of Elastomer Composites: The Effect of a Hybrid Carbon Black/Carbon Nanotubes Filler," International Journal of Applied and Physical Sciences, Dr K.Vivehananthan, vol. 4(3), pages 76-80.
    • Handle: RePEc:apa:ijapss:2018:p:76-80
    DOI: 10.20469/ijaps.4.50001-3
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    References listed on IDEAS

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    1. Mochamad Alvan Mifta Chusururi & Dendra Ravelia & Brahmanu Wisnu Saputro & Fikri Nafi’ul Ahmadi & Lukman Noerochiem & Budi Agung Kurniawan, 2018. "Comparison of corrosion inhibitor performance based on green corrosion inhibitor of extract leaf tobacco and commercial imidazoline inhibitor in a sweet environment at carbon steel AISI 1045 in NaCl 3," Journal of Applied and Physical Sciences, Prof. Vakhrushev Alexander, vol. 4(1), pages 14-25.
    2. Kannan Rassiah & M. M. H Megat Ahmad & Aidy Ali, 2016. "Effect on mechanical properties of rice Husk/E-Glass polypropylene hybrid composites using sodium hydroxide (NaOH)," Journal of Advances in Technology and Engineering Research, A/Professor Akbar A. Khatibi, vol. 2(4), pages 105-111.
    3. Ratnarin Narakhetudomsak & Tusanee Tondee, 2016. "Rapid Chemical Oxygen Demand Analysis by Total Organic Carbon Correlation," International Journal of Applied and Physical Sciences, Dr K.Vivehananthan, vol. 2(1), pages 1-6.
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