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Relaxation behavior of elastomer composites: The effect of a hybrid carbon black/carbon nanotubes filler

Author

Listed:
  • Mansurova I. A

    (Vyatka State University, Kirov, Russia)

  • Burkov A. A

    (Vyatka State University, Kirov, Russia)

  • Shilov I. B

    (Vyatka State University, Kirov, Russia)

  • Shirokova Ye.S

    (Vyatka State University, Kirov, Russia)

  • Dolgiy E. O

    (PK Kirov Tire, Kirov, Russia)

  • Khousainov A.Ð’

    (Kazan National Research Technological University, Kazan, Russia)

  • Belozerov V. S

    (Vyatka State University, Kirov, Russia)

Abstract

The article analyzes relaxation α-transition in elastomeric composites containing a hybrid carbon black/carbon nanotubes (CB/CNT) filler. According to the DMA data, the inclusion of hybrid particles CB/CNT in the filler leads to the expansion of the temperature dependences of the loss tangent (TanD) for all samples towards lower temperatures and the displacement of the position of the TanD maximum by a value from 4.0 up to 16 degrees in comparison with control vulcanizate. The DSC data indicate the presence of additional low-temperature α-relaxation transitions in modified vulcanizates (-123 ... -118 oC). The observed relaxation behavior of macromolecules is due to the appearance in the material of regions with less dense packing of macromolecules and, as a consequence, the expansion of their conformational set for segmental motion under low-temperature conditions. It guarantees getting a material with increased fatigue resistance and frost resistance.

Suggested Citation

  • Mansurova I. A & Burkov A. A & Shilov I. B & Shirokova Ye.S & Dolgiy E. O & Khousainov A.Ð’ & Belozerov V. S, 2018. "Relaxation behavior of elastomer composites: The effect of a hybrid carbon black/carbon nanotubes filler," Journal of Applied and Physical Sciences, Prof. Vakhrushev Alexander, vol. 4(2), pages 55-59.
    • Handle: RePEc:apb:japsss:2018:p:55-59
    DOI: 10.20474/japs-4.2.2
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    References listed on IDEAS

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    1. Farhana Umer & Nurettin Cetinkaya, 2017. "Transient analysis due to short circuit faults in wind hybrid systems," Journal of Advances in Technology and Engineering Research, A/Professor Akbar A. Khatibi, vol. 3(3), pages 89-100.
    2. Kannan Rassiah & M. M. H Megat Ahmad & Aidy Ali, 2016. "Effect on mechanical properties of rice Husk/E-Glass polypropylene hybrid composites using sodium hydroxide (NaOH)," Journal of Advances in Technology and Engineering Research, A/Professor Akbar A. Khatibi, vol. 2(4), pages 105-111.
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