Geochemical responses of a saline aquifer to CO 2 injection: experimental study on Guantao formation of Bohai Bay Basin, East China

Geochemical responses of saline aquifers toward large quantities of CO 2 injection are important to the monitoring and safety assessment of CO 2 storage. Detailed studies on water‐rock‐CO 2 interactions of non‐marine saline aquifers through three batch‐reaction experiments were carried out under simulated reservoir conditions (T = 100°C, P = 10 MPa). pH decreased by 1∼2 and TDS increased by 268 mg/L ∼561 mg/L. Water type evolved from original Cl·SO 4 ‐Na to HCO 3 Cl·SO 4 ‐Na with a water/rock ratio of 3:1. Chemical components of HCO 3 , Ca, Mg and K and trace elements of Al, Cr, Mn, Ni and Zn showed a significant increase post CO 2 injection. Heavy metals including Cr, Mn, Ni, and Zn in the post‐reaction water exceeded drinking water standards, indicating potential pollution to shallow fresh aquifers by brine/CO 2 leakage. K‐feldspar and albite were variably dissolved and kaolinite, chlorite, and Fe‐bearing minerals of pyrite and hematite were newly formed, confirmed by suspended materials in the post‐reaction water, red sediments on the bottom of the reactor, and mineral saturation indexes. δ-super-2H H2O shift was observed and discussed, which was not reported in previous water‐rock‐CO 2 interactions studies. One possible reason is geochemical processes of new clay minerals formation under low temperature causing water consumption and δ-super-2H H2O enriched in the residual water. The CO 2 saturation and fraction of DIC from CO 2 dissolution were calculated to be 23%–36% and 33%–49% under experimental conditions and it is suggested that they can be used for CO 2 storage capacity assessment.