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Decarboxylative alkenylation

Author

Listed:
  • Jacob T. Edwards

    (The Scripps Research Institute)

  • Rohan R. Merchant

    (The Scripps Research Institute)

  • Kyle S. McClymont

    (The Scripps Research Institute)

  • Kyle W. Knouse

    (The Scripps Research Institute)

  • Tian Qin

    (The Scripps Research Institute)

  • Lara R. Malins

    (The Scripps Research Institute)

  • Benjamin Vokits

    (Discovery Chemistry, Bristol-Myers Squibb)

  • Scott A. Shaw

    (Discovery Chemistry, Bristol-Myers Squibb)

  • Deng-Hui Bao

    (Asymchem Life Science (Tianjin), Tianjin Economic-technological Development Zone)

  • Fu-Liang Wei

    (Asymchem Life Science (Tianjin), Tianjin Economic-technological Development Zone)

  • Ting Zhou

    (Asymchem Life Science (Tianjin), Tianjin Economic-technological Development Zone)

  • Martin D. Eastgate

    (Chemical Development, Bristol-Myers Squibb, One Squibb Drive)

  • Phil S. Baran

    (The Scripps Research Institute)

Abstract

Starting with alkyl carboxylic acids, a simple olefin synthesis using any substitution pattern or geometry, based on amide-bond synthesis with nickel- or iron-based catalysis, is described.

Suggested Citation

  • Jacob T. Edwards & Rohan R. Merchant & Kyle S. McClymont & Kyle W. Knouse & Tian Qin & Lara R. Malins & Benjamin Vokits & Scott A. Shaw & Deng-Hui Bao & Fu-Liang Wei & Ting Zhou & Martin D. Eastgate &, 2017. "Decarboxylative alkenylation," Nature, Nature, vol. 545(7653), pages 213-218, May.
    • Handle: RePEc:nat:nature:v:545:y:2017:i:7653:d:10.1038_nature22307
    DOI: 10.1038/nature22307
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    Cited by:

    1. Xing-Wang Han & Xun Zhang & Youyun Zhou & Aizezi Maimaitiming & Xiu-Li Sun & Yanshan Gao & Peizhi Li & Boyu Zhu & Eugene Y.-X. Chen & Xiaokang Kuang & Yong Tang, 2024. "Circular olefin copolymers made de novo from ethylene and α-olefins," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Yunpeng Yin & Jinxin Wang & Jian Li, 2024. "A concise and scalable chemoenzymatic synthesis of prostaglandins," Nature Communications, Nature, vol. 15(1), pages 1-7, December.

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