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Cooperative electrocatalytic alcohol oxidation with electron-proton-transfer mediators

Author

Listed:
  • Artavazd Badalyan

    (University of Wisconsin-Madison)

  • Shannon S. Stahl

    (University of Wisconsin-Madison)

Abstract

A co-catalyst system for electrochemical alcohol oxidation composed of a bipyridine copper catalyst and an electron-proton-transfer mediator called TEMPO operates at much lower potential and is faster than TEMPO alone.

Suggested Citation

  • Artavazd Badalyan & Shannon S. Stahl, 2016. "Cooperative electrocatalytic alcohol oxidation with electron-proton-transfer mediators," Nature, Nature, vol. 535(7612), pages 406-410, July.
    • Handle: RePEc:nat:nature:v:535:y:2016:i:7612:d:10.1038_nature18008
    DOI: 10.1038/nature18008
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    Cited by:

    1. Min Liu & Tian Feng & Yanwei Wang & Guangsheng Kou & Qiuyan Wang & Qian Wang & Youai Qiu, 2023. "Metal-free electrochemical dihydroxylation of unactivated alkenes," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    2. Lei Fan & Xiaowan Bai & Chuan Xia & Xiao Zhang & Xunhua Zhao & Yang Xia & Zhen-Yu Wu & Yingying Lu & Yuanyue Liu & Haotian Wang, 2022. "CO2/carbonate-mediated electrochemical water oxidation to hydrogen peroxide," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    3. Ke Liu & Mengna Lei & Xin Li & Xuemei Zhang & Ying Zhang & Weigang Fan & Man-Bo Li & Sheng Zhang, 2024. "Paired electrocatalysis unlocks cross-dehydrogenative coupling of C(sp3)-H bonds using a pentacoordinated cobalt-salen catalyst," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    4. Cong Liu & Bingbao Mei & Zhaoping Shi & Zheng Jiang & Junjie Ge & Wei Xing & Ping Song & Weilin Xu, 2024. "Operando formation of highly efficient electrocatalysts induced by heteroatom leaching," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

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