IDEAS home Printed from https://ideas.repec.org/a/nat/nature/v524y2015i7565d10.1038_nature14875.html
   My bibliography  Save this article

Switching on elusive organometallic mechanisms with photoredox catalysis

Author

Listed:
  • Jack A. Terrett

    (Merck Center for Catalysis at Princeton University)

  • James D. Cuthbertson

    (Merck Center for Catalysis at Princeton University)

  • Valerie W. Shurtleff

    (Merck Center for Catalysis at Princeton University)

  • David W. C. MacMillan

    (Merck Center for Catalysis at Princeton University)

Abstract

Despite advances in carbon–carbon fragment couplings, the ability to forge carbon–oxygen bonds in a general fashion via nickel catalysis has been largely unsuccessful; here, visible-light-excited photoredox catalysts are shown to provide transient access to Ni(iii) species that readily participate in reductive elimination, leading to carbon–oxygen coupling.

Suggested Citation

  • Jack A. Terrett & James D. Cuthbertson & Valerie W. Shurtleff & David W. C. MacMillan, 2015. "Switching on elusive organometallic mechanisms with photoredox catalysis," Nature, Nature, vol. 524(7565), pages 330-334, August.
    • Handle: RePEc:nat:nature:v:524:y:2015:i:7565:d:10.1038_nature14875
    DOI: 10.1038/nature14875
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/nature14875
    File Function: Abstract
    Download Restriction: Access to the full text of the articles in this series is restricted.
    File URL: https://libkey.io/10.1038/nature14875?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Hanah Na & Liviu M. Mirica, 2022. "Deciphering the mechanism of the Ni-photocatalyzed C‒O cross-coupling reaction using a tridentate pyridinophane ligand," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    2. Yantao Li & Qianzhen Shao & Hengchi He & Chengjian Zhu & Xiao-Song Xue & Jin Xie, 2022. "Highly selective synthesis of all-carbon tetrasubstituted alkenes by deoxygenative alkenylation of carboxylic acids," Nature Communications, Nature, vol. 13(1), pages 1-8, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:nature:v:524:y:2015:i:7565:d:10.1038_nature14875. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.