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Switching on elusive organometallic mechanisms with photoredox catalysis

Author

Listed:
  • Jack A. Terrett

    (Merck Center for Catalysis at Princeton University)

  • James D. Cuthbertson

    (Merck Center for Catalysis at Princeton University)

  • Valerie W. Shurtleff

    (Merck Center for Catalysis at Princeton University)

  • David W. C. MacMillan

    (Merck Center for Catalysis at Princeton University)

Abstract

Despite advances in carbon–carbon fragment couplings, the ability to forge carbon–oxygen bonds in a general fashion via nickel catalysis has been largely unsuccessful; here, visible-light-excited photoredox catalysts are shown to provide transient access to Ni(iii) species that readily participate in reductive elimination, leading to carbon–oxygen coupling.

Suggested Citation

  • Jack A. Terrett & James D. Cuthbertson & Valerie W. Shurtleff & David W. C. MacMillan, 2015. "Switching on elusive organometallic mechanisms with photoredox catalysis," Nature, Nature, vol. 524(7565), pages 330-334, August.
    • Handle: RePEc:nat:nature:v:524:y:2015:i:7565:d:10.1038_nature14875
    DOI: 10.1038/nature14875
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    Cited by:

    1. Yantao Li & Qianzhen Shao & Hengchi He & Chengjian Zhu & Xiao-Song Xue & Jin Xie, 2022. "Highly selective synthesis of all-carbon tetrasubstituted alkenes by deoxygenative alkenylation of carboxylic acids," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    2. Hanah Na & Liviu M. Mirica, 2022. "Deciphering the mechanism of the Ni-photocatalyzed C‒O cross-coupling reaction using a tridentate pyridinophane ligand," Nature Communications, Nature, vol. 13(1), pages 1-11, December.

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