IDEAS home Printed from https://ideas.repec.org/a/nat/nature/v522y2015i7556d10.1038_nature14489.html
   My bibliography  Save this article

Multiple complexation of CO and related ligands to a main-group element

Author

Listed:
  • Holger Braunschweig

    (Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg)

  • Rian D. Dewhurst

    (Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg)

  • Florian Hupp

    (Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg)

  • Marco Nutz

    (Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg)

  • Krzysztof Radacki

    (Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg)

  • Christopher W. Tate

    (Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg)

  • Alfredo Vargas

    (School of Life Sciences, University of Sussex)

  • Qing Ye

    (Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg)

Abstract

Transition metal–ligand fragments are often able to bind and release several carbon monoxide molecules, such as the catalysts used in industrial-scale acetic acid synthesis and the active sites of hydrogenase enzymes, but main-group elements have never shown an ability to bind more than one carbon monoxide molecule; here a boron-based compound stable to moisture and air is synthesized and shown to contain multiple carbon monoxide units bound to the central boron atom.

Suggested Citation

  • Holger Braunschweig & Rian D. Dewhurst & Florian Hupp & Marco Nutz & Krzysztof Radacki & Christopher W. Tate & Alfredo Vargas & Qing Ye, 2015. "Multiple complexation of CO and related ligands to a main-group element," Nature, Nature, vol. 522(7556), pages 327-330, June.
    • Handle: RePEc:nat:nature:v:522:y:2015:i:7556:d:10.1038_nature14489
    DOI: 10.1038/nature14489
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/nature14489
    File Function: Abstract
    Download Restriction: Access to the full text of the articles in this series is restricted.
    File URL: https://libkey.io/10.1038/nature14489?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. David Biskup & Gregor Schnakenburg & René T. Boeré & Arturo Espinosa Ferao & Rainer K. Streubel, 2023. "Challenging an old paradigm by demonstrating transition metal-like chemistry at a neutral nonmetal center," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    2. Jun Fan & An-Ping Koh & Chi-Shiun Wu & Ming-Der Su & Cheuk-Wai So, 2024. "Carbon dioxide capture and functionalization by bis(N-heterocyclic carbene)-borylene complexes," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    3. Marcel Härterich & Alexander Matler & Rian D. Dewhurst & Andreas Sachs & Kai Oppel & Andreas Stoy & Holger Braunschweig, 2023. "A step-for-step main-group replica of the Fischer carbene synthesis at a borylene carbonyl," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    4. Liyan Cai & Bing Xu & Juanjuan Cheng & Fei Cong & Sebastian Riedel & Xuefeng Wang, 2024. "N2 cleavage by silylene and formation of H2Si(μ-N)2SiH2," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:nature:v:522:y:2015:i:7556:d:10.1038_nature14489. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.