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Dicalcium nitride as a two-dimensional electride with an anionic electron layer

Author

Listed:
  • Kimoon Lee

    (Frontier Research Center, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan)

  • Sung Wng Kim

    (Frontier Research Center, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
    Sungkyunkwan University, 300 Cheoncheon-dong, Jangan-gu, Suwon, Gyeonggi-do 440-746, South Korea)

  • Yoshitake Toda

    (Frontier Research Center, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan)

  • Satoru Matsuishi

    (Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan)

  • Hideo Hosono

    (Frontier Research Center, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
    Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan)

Abstract

The ionic crystal Ca2N is shown to be an electride in terms of [Ca2N]+·e−, with diffusive two-dimensional transport in dense electron layers.

Suggested Citation

  • Kimoon Lee & Sung Wng Kim & Yoshitake Toda & Satoru Matsuishi & Hideo Hosono, 2013. "Dicalcium nitride as a two-dimensional electride with an anionic electron layer," Nature, Nature, vol. 494(7437), pages 336-340, February.
    • Handle: RePEc:nat:nature:v:494:y:2013:i:7437:d:10.1038_nature11812
    DOI: 10.1038/nature11812
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    Cited by:

    1. Xiang-Rui Liu & Hanbin Deng & Yuntian Liu & Zhouyi Yin & Congrun Chen & Yu-Peng Zhu & Yichen Yang & Zhicheng Jiang & Zhengtai Liu & Mao Ye & Dawei Shen & Jia-Xin Yin & Kedong Wang & Qihang Liu & Yue Z, 2023. "Spectroscopic signature of obstructed surface states in SrIn2P2," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    2. Jiayi Chen & Mohammed Aliasgar & Fernando Buendia Zamudio & Tianyu Zhang & Yilin Zhao & Xu Lian & Lan Wen & Haozhou Yang & Wenping Sun & Sergey M. Kozlov & Wei Chen & Lei Wang, 2023. "Diversity of platinum-sites at platinum/fullerene interface accelerates alkaline hydrogen evolution," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    3. Raji Heyrovska, 2013. "Atomic and Ionic Radii of Elements and Bohr Radii from Ionization Potentials are Linked Through the Golden Ratio," International Journal of Sciences, Office ijSciences, vol. 2(03), pages 82-92, March.
    4. Seung Yong Lee & Dong Cheol Lim & Md Salman Khan & Jeong Yun Hwang & Hyung Sub Kim & Kyu Hyung Lee & Sung Wng Kim, 2023. "Magnetic quasi-atomic electrons driven reversible structural and magnetic transitions between electride and its hydrides," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

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