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Main-group elements as transition metals

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  • Philip P. Power

    (University of California, Davis, California 95616, USA)

Abstract

Elements in transition The chemistry of heavier main-group elements such as aluminium, silicon and phosphorus is very different from that of the lighter ones such as boron, carbon and nitrogen, yet discussions of this topic have been dominated by comparisons with the light elements. Philip Power's review focuses on advances in chemistry of the heavier main-group elements that reveal them as having more in common with the transition metals than the lighter members of the main groups. The concept of heavier main-group elements as 'transition metals' is supported by recent work showing that many of the new compounds react with small molecules such as H2, NH3, C2H4 and CO under mild conditions and display potential as catalysts.

Suggested Citation

  • Philip P. Power, 2010. "Main-group elements as transition metals," Nature, Nature, vol. 463(7278), pages 171-177, January.
    • Handle: RePEc:nat:nature:v:463:y:2010:i:7278:d:10.1038_nature08634
    DOI: 10.1038/nature08634
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    Cited by:

    1. Liyan Cai & Bing Xu & Juanjuan Cheng & Fei Cong & Sebastian Riedel & Xuefeng Wang, 2024. "N2 cleavage by silylene and formation of H2Si(μ-N)2SiH2," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    2. Shaozhi Du & Fanshu Cao & Xi Chen & Hua Rong & Haibin Song & Zhenbo Mo, 2023. "A silylene-stabilized ditin(0) complex and its conversion to methylditin cation and distannavinylidene," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Runbo Pei & Wenju Chang & Liancheng He & Tao Wang & Yue Zhao & Yong Liang & Xinping Wang, 2024. "Main-group compounds selectively activate natural gas alkanes under room temperature and atmospheric pressure," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    4. Sonia Bajo & Enrique Soto & Marta Fernández-Buenestado & Joaquín López-Serrano & Jesús Campos, 2024. "A low-coordinate platinum(0)-germylene for E–H bond activation and catalytic hydrodehalogenation," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    5. Marcel Härterich & Alexander Matler & Rian D. Dewhurst & Andreas Sachs & Kai Oppel & Andreas Stoy & Holger Braunschweig, 2023. "A step-for-step main-group replica of the Fischer carbene synthesis at a borylene carbonyl," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    6. Zhuchunguang Liu & Zhijun Wang & Huan Mu & Yihan Zhou & Jiliang Zhou & Zhaowen Dong, 2024. "Synthesis and redox catalysis of Carbodiphosphorane ligated stannylene," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    7. Fenghui Ye & Shishi Zhang & Qingqing Cheng & Yongde Long & Dong Liu & Rajib Paul & Yunming Fang & Yaqiong Su & Liangti Qu & Liming Dai & Chuangang Hu, 2023. "The role of oxygen-vacancy in bifunctional indium oxyhydroxide catalysts for electrochemical coupling of biomass valorization with CO2 conversion," Nature Communications, Nature, vol. 14(1), pages 1-14, December.

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