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A biomimetic high-capacity phenazine-based anolyte for aqueous organic redox flow batteries

Author

Listed:
  • Aaron Hollas

    (Pacific Northwest National Laboratory)

  • Xiaoliang Wei

    (Pacific Northwest National Laboratory
    Indiana University-Purdue University Indianapolis (IUPUI))

  • Vijayakumar Murugesan

    (Pacific Northwest National Laboratory)

  • Zimin Nie

    (Pacific Northwest National Laboratory)

  • Bin Li

    (Pacific Northwest National Laboratory)

  • David Reed

    (Pacific Northwest National Laboratory)

  • Jun Liu

    (Pacific Northwest National Laboratory)

  • Vincent Sprenkle

    (Pacific Northwest National Laboratory)

  • Wei Wang

    (Pacific Northwest National Laboratory)

Abstract

Aqueous soluble organic (ASO) redox-active materials have recently attracted significant attention as alternatives to traditional transition metal ions in redox flow batteries (RFB). However, reported reversible capacities of ASO are often substantially lower than their theoretical values based on the reported maximum solubilities. Here, we describe a phenazine-based ASO compound with an exceptionally high reversible capacity that exceeds 90% of its theoretical value. By strategically modifying the phenazine molecular structure, we demonstrate an increased solubility from near-zero with pristine phenazine to as much as 1.8 M while also shifting its redox potential by more than 400 mV. An RFB based on a phenazine derivative (7,8-dihydroxyphenazine-2-sulfonic acid) at its near-saturation concentration exhibits an operating voltage of 1.4 V with a reversible anolyte capacity of 67 Ah l−1 and a capacity retention of 99.98% per cycle over 500 cycles.

Suggested Citation

  • Aaron Hollas & Xiaoliang Wei & Vijayakumar Murugesan & Zimin Nie & Bin Li & David Reed & Jun Liu & Vincent Sprenkle & Wei Wang, 2018. "A biomimetic high-capacity phenazine-based anolyte for aqueous organic redox flow batteries," Nature Energy, Nature, vol. 3(6), pages 508-514, June.
    • Handle: RePEc:nat:natene:v:3:y:2018:i:6:d:10.1038_s41560-018-0167-3
    DOI: 10.1038/s41560-018-0167-3
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    Citations

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    Cited by:

    1. Dominik Emmel & Simon Kunz & Nick Blume & Yongchai Kwon & Thomas Turek & Christine Minke & Daniel Schröder, 2023. "Benchmarking organic active materials for aqueous redox flow batteries in terms of lifetime and cost," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    2. Xie, Heping & Wu, Yifan & Liu, Tao & Wang, Fuhuan & Chen, Bin & Liang, Bin, 2020. "Low-energy-consumption electrochemical CO2 capture driven by biomimetic phenazine derivatives redox medium," Applied Energy, Elsevier, vol. 259(C).
    3. Leung, P. & Martin, T. & Xu, Q. & Flox, C. & Mohamad, M.R. & Palma, J. & Rodchanarowan, A. & Zhu, X. & Xing, W.W. & Shah, A.A., 2021. "A new aqueous all-organic flow battery with high cell voltage in acidic electrolytes," Applied Energy, Elsevier, vol. 282(PA).
    4. Dominic Hey & Rajesh B. Jethwa & Nadia L. Farag & Bernardine L. D. Rinkel & Evan Wenbo Zhao & Clare P. Grey, 2023. "Identifying and preventing degradation in flavin mononucleotide-based redox flow batteries via NMR and EPR spectroscopy," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    5. Park, Gyunho & Jeong, Hayoung & Lee, Wonmi & Han, Jeong Woo & Chang, Duck Rye & Kwon, Yongchai, 2024. "Scaled-up aqueous redox flow battery using anthraquinone negalyte and vanadium posilyte with inorganic additive," Applied Energy, Elsevier, vol. 353(PB).
    6. Igor Iwakiri & Tiago Antunes & Helena Almeida & João P. Sousa & Rita Bacelar Figueira & Adélio Mendes, 2021. "Redox Flow Batteries: Materials, Design and Prospects," Energies, MDPI, vol. 14(18), pages 1-45, September.
    7. Gabriel S. Nambafu & Aaron M. Hollas & Shuyuan Zhang & Peter S. Rice & Daria Boglaienko & John L. Fulton & Miller Li & Qian Huang & Yu Zhu & David M. Reed & Vincent L. Sprenkle & Guosheng Li, 2024. "Phosphonate-based iron complex for a cost-effective and long cycling aqueous iron redox flow battery," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    8. Liang, Mengjun & Karthick, Ramalingam & Wei, Qiang & Dai, Jinhong & Jiang, Zhuosheng & Chen, Xuncai & Oo, Than Zaw & Aung, Su Htike & Chen, Fuming, 2022. "The progress and prospect of the solar-driven photoelectrochemical desalination," Renewable and Sustainable Energy Reviews, Elsevier, vol. 155(C).

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