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A half-wave rectified alternating current electrochemical method for uranium extraction from seawater

Author

Listed:
  • Chong Liu

    (Stanford University)

  • Po-Chun Hsu

    (Stanford University)

  • Jin Xie

    (Stanford University)

  • Jie Zhao

    (Stanford University)

  • Tong Wu

    (Stanford University)

  • Haotian Wang

    (Stanford University
    † Present address: Rowland Institute at Harvard, Harvard University, Cambridge, Massachusetts 02142, USA.)

  • Wei Liu

    (Stanford University)

  • Jinsong Zhang

    (Stanford University)

  • Steven Chu

    (Stanford University
    Stanford University)

  • Yi Cui

    (Stanford University
    Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory)

Abstract

In total there is hundreds of times more uranium in sea water than on land, but extracting it for use in nuclear power generation is challenging due to its low concentration (∼3 ppb) and the high salinity background. Current approaches based on sorbent materials are limited due to their surface-based physicochemical adsorption nature. Here we use a half-wave rectified alternating current electrochemical (HW-ACE) method for uranium extraction from sea water based on an amidoxime-functionalized carbon electrode. The amidoxime functionalization enables surface specific binding to uranyl ions, while the electric field can migrate the ions to the electrode and induce electrodeposition of uranium compounds, forming charge-neutral species. Extraction is not limited by the electrode surface area, and the alternating manner of the applied voltage prevents unwanted cations from blocking the active sites and avoids water splitting. The HW-ACE method achieved a ninefold higher uranium extraction capacity (1,932 mg g−1) without saturation and fourfold faster kinetics than conventional physicochemical methods using uranium-spiked sea water.

Suggested Citation

  • Chong Liu & Po-Chun Hsu & Jin Xie & Jie Zhao & Tong Wu & Haotian Wang & Wei Liu & Jinsong Zhang & Steven Chu & Yi Cui, 2017. "A half-wave rectified alternating current electrochemical method for uranium extraction from seawater," Nature Energy, Nature, vol. 2(4), pages 1-8, April.
    • Handle: RePEc:nat:natene:v:2:y:2017:i:4:d:10.1038_nenergy.2017.7
    DOI: 10.1038/nenergy.2017.7
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    Cited by:

    1. Zhou, Lean & Liao, Chengmei & Li, Tian & An, Jingkun & Du, Qing & Wan, Lili & Li, Nan & Pan, Xiaoqiang & Wang, Xin, 2018. "Regeneration of activated carbon air-cathodes by half-wave rectified alternating fields in microbial fuel cells," Applied Energy, Elsevier, vol. 219(C), pages 199-206.

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