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Advances in lithium–sulfur batteries based on multifunctional cathodes and electrolytes

Author

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  • Quan Pang

    (University of Waterloo)

  • Xiao Liang

    (University of Waterloo)

  • Chun Yuen Kwok

    (University of Waterloo)

  • Linda F. Nazar

    (University of Waterloo)

Abstract

Amid burgeoning environmental concerns, electrochemical energy storage has rapidly gained momentum. Among the contenders in the ‘beyond lithium’ energy storage arena, the lithium–sulfur (Li–S) battery has emerged as particularly promising, owing to its potential to reversibly store considerable electrical energy at low cost. Whether or not Li–S energy storage will be able to fulfil this potential depends on simultaneously solving many aspects of its underlying conversion chemistry. Here, we review recent developments in tackling the dissolution of polysulfides — a fundamental problem in Li–S batteries — focusing on both experimental and computational approaches to tailor the chemical interactions between the sulfur host materials and polysulfides. We also discuss smart cathode architectures enabled by recent materials engineering, especially for high areal sulfur loading, as well as innovative electrolyte design to control the solubility of polysulfides. Key factors that allow long-life and high-loading Li–S batteries are summarized.

Suggested Citation

  • Quan Pang & Xiao Liang & Chun Yuen Kwok & Linda F. Nazar, 2016. "Advances in lithium–sulfur batteries based on multifunctional cathodes and electrolytes," Nature Energy, Nature, vol. 1(9), pages 1-11, September.
  • Handle: RePEc:nat:natene:v:1:y:2016:i:9:d:10.1038_nenergy.2016.132
    DOI: 10.1038/nenergy.2016.132
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    Cited by:

    1. Shuangyan Lang & Seung-Ho Yu & Xinran Feng & Mihail R. Krumov & Héctor D. Abruña, 2022. "Understanding the lithium–sulfur battery redox reactions via operando confocal Raman microscopy," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    2. Tang, Kejian & Peng, Xiangqi & Chen, Shuijiao & Song, Fei & Liu, Zhichao & Hu, Jian & Xie, Xiuqiang & Wu, Zhenjun, 2022. "Hierarchically porous carbon derived from delignified biomass for high sulfur-loading room-temperature sodium-sulfur batteries," Renewable Energy, Elsevier, vol. 201(P1), pages 832-840.
    3. Li, Bin, 2024. "Leading role of natural resources, eco-efficiency assessment, and energy transition in environmental sustainability: A depth of digital transformation," Resources Policy, Elsevier, vol. 94(C).
    4. Fu Liu & Wenqing Lu & Jiaqiang Huang & Vanessa Pimenta & Steven Boles & Rezan Demir-Cakan & Jean-Marie Tarascon, 2023. "Detangling electrolyte chemical dynamics in lithium sulfur batteries by operando monitoring with optical resonance combs," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    5. Liu, Ying & Lee, Dong Jun & Ahn, Hyo-Jun & Nam, Sang Yong & Cho, Kwon-Koo & Ahn, Jou-Hyeon, 2023. "Waste coffee grounds-derived carbon: Nanoarchitectured pore-structure regulation for sustainable room-temperature sodium–sulfur batteries," Renewable Energy, Elsevier, vol. 212(C), pages 865-874.
    6. Christian Prehal & Jean-Marc Mentlen & Sara Drvarič Talian & Alen Vizintin & Robert Dominko & Heinz Amenitsch & Lionel Porcar & Stefan A. Freunberger & Vanessa Wood, 2022. "On the nanoscale structural evolution of solid discharge products in lithium-sulfur batteries using operando scattering," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    7. Jiashen Meng & Xufeng Hong & Zhitong Xiao & Linhan Xu & Lujun Zhu & Yongfeng Jia & Fang Liu & Liqiang Mai & Quanquan Pang, 2024. "Rapid-charging aluminium-sulfur batteries operated at 85 °C with a quaternary molten salt electrolyte," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    8. Chao Ye & Huanyu Jin & Jieqiong Shan & Yan Jiao & Huan Li & Qinfen Gu & Kenneth Davey & Haihui Wang & Shi-Zhang Qiao, 2021. "A Mo5N6 electrocatalyst for efficient Na2S electrodeposition in room-temperature sodium-sulfur batteries," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    9. Xun Sun & Yue Qiu & Bo Jiang & Zhaoyu Chen & Chenghao Zhao & Hao Zhou & Li Yang & Lishuang Fan & Yu Zhang & Naiqing Zhang, 2023. "Isolated Fe-Co heteronuclear diatomic sites as efficient bifunctional catalysts for high-performance lithium-sulfur batteries," Nature Communications, Nature, vol. 14(1), pages 1-10, December.

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