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Metal-organic framework glasses with permanent accessible porosity

Author

Listed:
  • Chao Zhou

    (University of Cambridge
    Aalborg University)

  • Louis Longley

    (University of Cambridge)

  • Andraž Krajnc

    (National Institute of Chemistry)

  • Glen J. Smales

    (University College London
    Harwell Science and Innovation Campus)

  • Ang Qiao

    (Wuhan University of Technology)

  • Ilknur Erucar

    (Ozyegin University)

  • Cara M. Doherty

    (Commonwealth Scientific and Industrial Research Organisation)

  • Aaron W. Thornton

    (Commonwealth Scientific and Industrial Research Organisation)

  • Anita J. Hill

    (Commonwealth Scientific and Industrial Research Organisation)

  • Christopher W. Ashling

    (University of Cambridge)

  • Omid T. Qazvini

    (Massey University)

  • Seok J. Lee

    (Massey University)

  • Philip A. Chater

    (Harwell Science and Innovation Campus)

  • Nicholas J. Terrill

    (Harwell Science and Innovation Campus)

  • Andrew J. Smith

    (Harwell Science and Innovation Campus)

  • Yuanzheng Yue

    (Aalborg University
    Wuhan University of Technology
    Qilu University of Technology)

  • Gregor Mali

    (National Institute of Chemistry)

  • David A. Keen

    (Rutherford Appleton Laboratory Harwell Campus)

  • Shane G. Telfer

    (Massey University)

  • Thomas D. Bennett

    (University of Cambridge)

Abstract

To date, only several microporous, and even fewer nanoporous, glasses have been produced, always via post synthesis acid treatment of phase separated dense materials, e.g. Vycor glass. In contrast, high internal surface areas are readily achieved in crystalline materials, such as metal-organic frameworks (MOFs). It has recently been discovered that a new family of melt quenched glasses can be produced from MOFs, though they have thus far lacked the accessible and intrinsic porosity of their crystalline precursors. Here, we report the first glasses that are permanently and reversibly porous toward incoming gases, without post-synthetic treatment. We characterize the structure of these glasses using a range of experimental techniques, and demonstrate pores in the range of 4 – 8 Å. The discovery of MOF glasses with permanent accessible porosity reveals a new category of porous glass materials that are elevated beyond conventional inorganic and organic porous glasses by their diversity and tunability.

Suggested Citation

  • Chao Zhou & Louis Longley & Andraž Krajnc & Glen J. Smales & Ang Qiao & Ilknur Erucar & Cara M. Doherty & Aaron W. Thornton & Anita J. Hill & Christopher W. Ashling & Omid T. Qazvini & Seok J. Lee & P, 2018. "Metal-organic framework glasses with permanent accessible porosity," Nature Communications, Nature, vol. 9(1), pages 1-9, December.
  • Handle: RePEc:nat:natcom:v:9:y:2018:i:1:d:10.1038_s41467-018-07532-z
    DOI: 10.1038/s41467-018-07532-z
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    Cited by:

    1. Wei Zhang & Yanchen Liu & Henrik S. Jeppesen & Nicola Pinna, 2024. "Stöber method to amorphous metal-organic frameworks and coordination polymers," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    2. Oksana Smirnova & Roman Sajzew & Sarah Jasmin Finkelmeyer & Teymur Asadov & Sayan Chattopadhyay & Torsten Wieduwilt & Aaron Reupert & Martin Presselt & Alexander Knebel & Lothar Wondraczek, 2024. "Micro-optical elements from optical-quality ZIF-62 hybrid glasses by hot imprinting," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. Louis Frentzel-Beyme & Pascal Kolodzeiski & Jan-Benedikt Weiß & Andreas Schneemann & Sebastian Henke, 2022. "Quantification of gas-accessible microporosity in metal-organic framework glasses," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    4. Zihui Zhang & Yingbo Zhao, 2024. "Transparent and high-porosity aluminum alkoxide network-forming glasses," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    5. Wen-Long Xue & Pascal Kolodzeiski & Hanna Aucharova & Suresh Vasa & Athanasios Koutsianos & Roman Pallach & Jianbo Song & Louis Frentzel-Beyme & Rasmus Linser & Sebastian Henke, 2024. "Highly porous metal-organic framework liquids and glasses via a solvent-assisted linker exchange strategy of ZIF-8," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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