IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v9y2018i1d10.1038_s41467-018-07292-w.html
   My bibliography  Save this article

Coherent multidimensional spectroscopy of dilute gas-phase nanosystems

Author

Listed:
  • Lukas Bruder

    (University of Freiburg)

  • Ulrich Bangert

    (University of Freiburg)

  • Marcel Binz

    (University of Freiburg)

  • Daniel Uhl

    (University of Freiburg)

  • Romain Vexiau

    (CNRS, Université Paris-Sud, ENS Cachan, Université Paris-Saclay)

  • Nadia Bouloufa-Maafa

    (CNRS, Université Paris-Sud, ENS Cachan, Université Paris-Saclay)

  • Olivier Dulieu

    (CNRS, Université Paris-Sud, ENS Cachan, Université Paris-Saclay)

  • Frank Stienkemeier

    (University of Freiburg
    University of Freiburg)

Abstract

Two-dimensional electronic spectroscopy (2DES) is one of the most powerful spectroscopic techniques with unique sensitivity to couplings, coherence properties and real-time dynamics of a quantum system. While successfully applied to a variety of condensed phase samples, high precision experiments on isolated systems in the gas phase have been so far precluded by insufficient sensitivity. However, such experiments are essential for a precise understanding of fundamental mechanisms and to avoid misinterpretations. Here, we solve this issue by extending 2DES to isolated nanosystems in the gas phase prepared by helium nanodroplet isolation in a molecular beam-type experiment. This approach uniquely provides high flexibility in synthesizing tailored, quantum state-selected model systems of single and many-body character. In a model study of weakly-bound Rb2 and Rb3 molecules we demonstrate the method’s unique capacity to elucidate interactions and dynamics in tailored quantum systems, thereby also bridging the gap to experiments in ultracold quantum science.

Suggested Citation

  • Lukas Bruder & Ulrich Bangert & Marcel Binz & Daniel Uhl & Romain Vexiau & Nadia Bouloufa-Maafa & Olivier Dulieu & Frank Stienkemeier, 2018. "Coherent multidimensional spectroscopy of dilute gas-phase nanosystems," Nature Communications, Nature, vol. 9(1), pages 1-7, December.
  • Handle: RePEc:nat:natcom:v:9:y:2018:i:1:d:10.1038_s41467-018-07292-w
    DOI: 10.1038/s41467-018-07292-w
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-018-07292-w
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-018-07292-w?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ulrich Bangert & Frank Stienkemeier & Lukas Bruder, 2022. "High-resolution two-dimensional electronic spectroscopy reveals the homogeneous line profile of chromophores solvated in nanoclusters," Nature Communications, Nature, vol. 13(1), pages 1-8, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:9:y:2018:i:1:d:10.1038_s41467-018-07292-w. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.