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High-resolution two-dimensional electronic spectroscopy reveals the homogeneous line profile of chromophores solvated in nanoclusters

Author

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  • Ulrich Bangert

    (University of Freiburg)

  • Frank Stienkemeier

    (University of Freiburg)

  • Lukas Bruder

    (University of Freiburg)

Abstract

Doped clusters in the gas phase provide nanoconfined model systems for the study of system-bath interactions. To gain insight into interaction mechanisms between chromophores and their environment, the ensemble inhomogeneity has to be lifted and the homogeneous line profile must be accessed. However, such measurements are very challenging at the low particle densities and low signal levels in cluster beam experiments. Here, we dope cryogenic rare-gas clusters with phthalocyanine molecules and apply action-detected two-dimensional electronic spectroscopy to gain insight into the local molecule-cluster environment for solid and superfluid cluster species. The high-resolution homogeneous linewidth analysis provides a benchmark for the theoretical modelling of binding configurations and shows a promising route for high-resolution molecular two-dimensional spectroscopy.

Suggested Citation

  • Ulrich Bangert & Frank Stienkemeier & Lukas Bruder, 2022. "High-resolution two-dimensional electronic spectroscopy reveals the homogeneous line profile of chromophores solvated in nanoclusters," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-31021-z
    DOI: 10.1038/s41467-022-31021-z
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    References listed on IDEAS

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    1. Andreas Wituschek & Lukas Bruder & Enrico Allaria & Ulrich Bangert & Marcel Binz & Roberto Borghes & Carlo Callegari & Giulio Cerullo & Paolo Cinquegrana & Luca Giannessi & Miltcho Danailov & Alexande, 2020. "Tracking attosecond electronic coherences using phase-manipulated extreme ultraviolet pulses," Nature Communications, Nature, vol. 11(1), pages 1-7, December.
    2. Lukas Bruder & Ulrich Bangert & Marcel Binz & Daniel Uhl & Romain Vexiau & Nadia Bouloufa-Maafa & Olivier Dulieu & Frank Stienkemeier, 2018. "Coherent multidimensional spectroscopy of dilute gas-phase nanosystems," Nature Communications, Nature, vol. 9(1), pages 1-7, December.
    3. Sebastian Roeding & Tobias Brixner, 2018. "Coherent two-dimensional electronic mass spectrometry," Nature Communications, Nature, vol. 9(1), pages 1-9, December.
    4. Bernhard Thaler & Sascha Ranftl & Pascal Heim & Stefan Cesnik & Leonhard Treiber & Ralf Meyer & Andreas W. Hauser & Wolfgang E. Ernst & Markus Koch, 2018. "Femtosecond photoexcitation dynamics inside a quantum solvent," Nature Communications, Nature, vol. 9(1), pages 1-6, December.
    5. M. L. Cowan & B. D. Bruner & N. Huse & J. R. Dwyer & B. Chugh & E. T. J. Nibbering & T. Elsaesser & R. J. D. Miller, 2005. "Ultrafast memory loss and energy redistribution in the hydrogen bond network of liquid H2O," Nature, Nature, vol. 434(7030), pages 199-202, March.
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