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Negatively charged nanoporous membrane for a dendrite-free alkaline zinc-based flow battery with long cycle life

Author

Listed:
  • Zhizhang Yuan

    (Chinese Academy of Sciences)

  • Xiaoqi Liu

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Wenbin Xu

    (Chinese Academy of Sciences)

  • Yinqi Duan

    (Chinese Academy of Sciences)

  • Huamin Zhang

    (Chinese Academy of Sciences
    Collaborative Innovation Center of Chemistry for Energy Materials (iChEM))

  • Xianfeng Li

    (Chinese Academy of Sciences
    Collaborative Innovation Center of Chemistry for Energy Materials (iChEM))

Abstract

Alkaline zinc-based flow batteries are regarded to be among the best choices for electric energy storage. Nevertheless, application is challenged by the issue of zinc dendrite/accumulation. Here, we report a negatively charged nanoporous membrane for a dendrite-free alkaline zinc-based flow battery with long cycle life. Free of zinc dendrite/accumulation, stable performance is afforded for ∼240 cycles at current densities ranging from 80 to 160 mA cm−2 using the negatively charged nanoporous membrane. Furthermore, 8 h and 7 h plating/stripping processes at 40 mA cm−2 yield an average energy efficiency of 91.92% and an areal discharge capacity above 130 mAh cm−2. A peak power density of 1056 mW cm−2 is achieved at 1040 mA cm−2. This study may provide an effective way to address the issue of zinc dendrite/accumulation for zinc-based batteries and accelerate the advancement of these batteries.

Suggested Citation

  • Zhizhang Yuan & Xiaoqi Liu & Wenbin Xu & Yinqi Duan & Huamin Zhang & Xianfeng Li, 2018. "Negatively charged nanoporous membrane for a dendrite-free alkaline zinc-based flow battery with long cycle life," Nature Communications, Nature, vol. 9(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:9:y:2018:i:1:d:10.1038_s41467-018-06209-x
    DOI: 10.1038/s41467-018-06209-x
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    Cited by:

    1. Xu, Zhicheng & Fan, Qi & Li, Yang & Wang, Jun & Lund, Peter D., 2020. "Review of zinc dendrite formation in zinc bromine redox flow battery," Renewable and Sustainable Energy Reviews, Elsevier, vol. 127(C).
    2. Raymond Leopold Heydorn & Jana Niebusch & David Lammers & Marion Görke & Georg Garnweitner & Katrin Dohnt & Rainer Krull, 2022. "Production and Characterization of Bacterial Cellulose Separators for Nickel-Zinc Batteries," Energies, MDPI, vol. 15(15), pages 1-20, August.
    3. Caixing Wang & Guoyuan Gao & Yaqiong Su & Ju Xie & Dunyong He & Xuemei Wang & Yanrong Wang & Yonggang Wang, 2024. "High-voltage and dendrite-free zinc-iodine flow battery," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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