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Combining CO2 reduction with propane oxidative dehydrogenation over bimetallic catalysts

Author

Listed:
  • Elaine Gomez

    (Columbia University)

  • Shyam Kattel

    (Brookhaven National Laboratory)

  • Binhang Yan

    (Brookhaven National Laboratory)

  • Siyu Yao

    (Brookhaven National Laboratory)

  • Ping Liu

    (Brookhaven National Laboratory)

  • Jingguang G. Chen

    (Columbia University
    Brookhaven National Laboratory)

Abstract

The inherent variability and insufficiencies in the co-production of propylene from steam crackers has raised concerns regarding the global propylene production gap and has directed industry to develop more on-purpose propylene technologies. The oxidative dehydrogenation of propane by CO2 (CO2-ODHP) can potentially fill this gap while consuming a greenhouse gas. Non-precious FeNi and precious NiPt catalysts supported on CeO2 have been identified as promising catalysts for CO2-ODHP and dry reforming, respectively, in flow reactor studies conducted at 823 K. In-situ X-ray absorption spectroscopy measurements revealed the oxidation states of metals under reaction conditions and density functional theory calculations were utilized to identify the most favorable reaction pathways over the two types of catalysts.

Suggested Citation

  • Elaine Gomez & Shyam Kattel & Binhang Yan & Siyu Yao & Ping Liu & Jingguang G. Chen, 2018. "Combining CO2 reduction with propane oxidative dehydrogenation over bimetallic catalysts," Nature Communications, Nature, vol. 9(1), pages 1-6, December.
    • Handle: RePEc:nat:natcom:v:9:y:2018:i:1:d:10.1038_s41467-018-03793-w
    DOI: 10.1038/s41467-018-03793-w
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    Cited by:

    1. Xinlong Ma & Haibin Yin & Zhengtian Pu & Xinyan Zhang & Sunpei Hu & Tao Zhou & Weizhe Gao & Laihao Luo & Hongliang Li & Jie Zeng, 2024. "Propane wet reforming over PtSn nanoparticles on γ-Al2O3 for acetone synthesis," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    2. Feilong Xing & Jiamin Ma & Ken-ichi Shimizu & Shinya Furukawa, 2022. "High-entropy intermetallics on ceria as efficient catalysts for the oxidative dehydrogenation of propane using CO2," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    3. Jalid, Fatima & Khan, Tuhin Suvra & Haider, M. Ali, 2021. "Exploring bimetallic alloy catalysts of Co, Pd and Cu for CO2 reduction combined with ethane dehydrogenation," Applied Energy, Elsevier, vol. 299(C).

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