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Toughness and strength of nanocrystalline graphene

Author

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  • Ashivni Shekhawat

    (Lawrence Berkeley National Laboratory
    University of California, 324 Hearst Memorial Mining Building, MC 1760, Berkeley, California 94720, USA
    Miller Institute for Basic Research in Science)

  • Robert O. Ritchie

    (Lawrence Berkeley National Laboratory
    University of California, 324 Hearst Memorial Mining Building, MC 1760, Berkeley, California 94720, USA)

Abstract

Pristine monocrystalline graphene is claimed to be the strongest material known with remarkable mechanical and electrical properties. However, graphene made with scalable fabrication techniques is polycrystalline and contains inherent nanoscale line and point defects—grain boundaries and grain-boundary triple junctions—that lead to significant statistical fluctuations in toughness and strength. These fluctuations become particularly pronounced for nanocrystalline graphene where the density of defects is high. Here we use large-scale simulation and continuum modelling to show that the statistical variation in toughness and strength can be understood with ‘weakest-link’ statistics. We develop the first statistical theory of toughness in polycrystalline graphene, and elucidate the nanoscale origins of the grain-size dependence of its strength and toughness. Our results should lead to more reliable graphene device design, and provide a framework to interpret experimental results in a broad class of two-dimensional materials.

Suggested Citation

  • Ashivni Shekhawat & Robert O. Ritchie, 2016. "Toughness and strength of nanocrystalline graphene," Nature Communications, Nature, vol. 7(1), pages 1-8, April.
    • Handle: RePEc:nat:natcom:v:7:y:2016:i:1:d:10.1038_ncomms10546
    DOI: 10.1038/ncomms10546
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    Cited by:

    1. Zezhu Zeng & Xingchen Shen & Ruihuan Cheng & Olivier Perez & Niuchang Ouyang & Zheyong Fan & Pierric Lemoine & Bernard Raveau & Emmanuel Guilmeau & Yue Chen, 2024. "Pushing thermal conductivity to its lower limit in crystals with simple structures," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    2. Yiming Song & Xiang Gao & Rémy Pawlak & Shuyu Huang & Antoine Hinaut & Thilo Glatzel & Oded Hod & Michael Urbakh & Ernst Meyer, 2024. "Non-Amontons frictional behaviors of grain boundaries at layered material interfaces," Nature Communications, Nature, vol. 15(1), pages 1-8, December.

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