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Atomistic understandings of reduced graphene oxide as an ultrathin-film nanoporous membrane for separations

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  • Li-Chiang Lin

    (Massachusetts Institute of Technology
    Delft University of Technology)

  • Jeffrey C. Grossman

    (Massachusetts Institute of Technology)

Abstract

The intrinsic defects in reduced graphene oxide (rGO) formed during reduction processes can act as nanopores, making rGO a promising ultrathin-film membrane candidate for separations. To assess the potential of rGO for such applications, molecular dynamics techniques are employed to understand the defect formation in rGO and their separation performance in water desalination and natural gas purification. We establish the relationship between rGO synthesis parameters and defect sizes, resulting in a potential means to control the size of nanopores in rGO. Furthermore, our results show that rGO membranes obtained under properly chosen synthesis conditions can achieve effective separations and provide significantly higher permeate fluxes than currently available membranes.

Suggested Citation

  • Li-Chiang Lin & Jeffrey C. Grossman, 2015. "Atomistic understandings of reduced graphene oxide as an ultrathin-film nanoporous membrane for separations," Nature Communications, Nature, vol. 6(1), pages 1-7, November.
  • Handle: RePEc:nat:natcom:v:6:y:2015:i:1:d:10.1038_ncomms9335
    DOI: 10.1038/ncomms9335
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    Cited by:

    1. Rezakazemi, Mashallah & Arabi Shamsabadi, Ahmad & Lin, Haiqing & Luis, Patricia & Ramakrishna, Seeram & Aminabhavi, Tejraj M., 2021. "Sustainable MXenes-based membranes for highly energy-efficient separations," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    2. Andrzej Olejniczak & Ruslan A. Rymzhanov, 2023. "From nanohole to ultralong straight nanochannel fabrication in graphene oxide with swift heavy ions," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    3. Yaxin Shi & Zhibin Guo & Qiang Fu & Xinyuan Shen & Zhongming Zhang & Wenjia Sun & Jinqiang Wang & Junliang Sun & Zizhu Zhang & Tong Liu & Zhen Gu & Zhibo Liu, 2023. "Localized nuclear reaction breaks boron drug capsules loaded with immune adjuvants for cancer immunotherapy," Nature Communications, Nature, vol. 14(1), pages 1-15, December.

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