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Induction and control of supramolecular chirality by light in self-assembled helical nanostructures

Author

Listed:
  • Jisung Kim

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Jinhee Lee

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Woo Young Kim

    (KAIST)

  • Hyungjun Kim

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Sanghwa Lee

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Hee Chul Lee

    (KAIST)

  • Yoon Sup Lee

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Myungeun Seo

    (Graduate School of Nanoscience and Technology, KAIST)

  • Sang Youl Kim

    (Korea Advanced Institute of Science and Technology (KAIST))

Abstract

Evolution of supramolecular chirality from self-assembly of achiral compounds and control over its handedness is closely related to the evolution of life and development of supramolecular materials with desired handedness. Here we report a system where the entire process of induction, control and locking of supramolecular chirality can be manipulated by light. Combination of triphenylamine and diacetylene moieties in the molecular structure allows photoinduced self-assembly of the molecule into helical aggregates in a chlorinated solvent by visible light and covalent fixation of the aggregate via photopolymerization by ultraviolet light, respectively. By using visible circularly polarized light, the supramolecular chirality of the resulting aggregates is selectively and reversibly controlled by its rotational direction, and the desired supramolecular chirality can be arrested by irradiation with ultraviolet circularly polarized light. This methodology opens a route to ward the formation of supramolecular chiral conducting nanostructures from the self-assembly of achiral molecules.

Suggested Citation

  • Jisung Kim & Jinhee Lee & Woo Young Kim & Hyungjun Kim & Sanghwa Lee & Hee Chul Lee & Yoon Sup Lee & Myungeun Seo & Sang Youl Kim, 2015. "Induction and control of supramolecular chirality by light in self-assembled helical nanostructures," Nature Communications, Nature, vol. 6(1), pages 1-8, November.
    • Handle: RePEc:nat:natcom:v:6:y:2015:i:1:d:10.1038_ncomms7959
    DOI: 10.1038/ncomms7959
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    Cited by:

    1. Stephen J. Klawa & Michelle Lee & Kyle D. Riker & Tengyue Jian & Qunzhao Wang & Yuan Gao & Margaret L. Daly & Shreeya Bhonge & W. Seth Childers & Tolulope O. Omosun & Anil K. Mehta & David G. Lynn & R, 2024. "Uncovering supramolecular chirality codes for the design of tunable biomaterials," Nature Communications, Nature, vol. 15(1), pages 1-16, December.
    2. Semih Sevim & Alessandro Sorrenti & João Pedro Vale & Zoubir El-Hachemi & Salvador Pané & Andreas D. Flouris & Tiago Sotto Mayor & Josep Puigmartí-Luis, 2022. "Chirality transfer from a 3D macro shape to the molecular level by controlling asymmetric secondary flows," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    3. Kuo Fu & Yanli Zhao & Guofeng Liu, 2024. "Pathway-directed recyclable chirality inversion of coordinated supramolecular polymers," Nature Communications, Nature, vol. 15(1), pages 1-13, December.

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