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Methane hydrate formation in confined nanospace can surpass nature

Author

Listed:
  • Mirian E. Casco

    (Laboratorio de Materiales Avanzados, Universidad de Alicante)

  • Joaquín Silvestre-Albero

    (Laboratorio de Materiales Avanzados, Universidad de Alicante)

  • Anibal J. Ramírez-Cuesta

    (Oak Ridge National Laboratory)

  • Fernando Rey

    (Instituto de Tecnología Química, Universidad Politécnica de Valencia-CSIC)

  • Jose L. Jordá

    (Instituto de Tecnología Química, Universidad Politécnica de Valencia-CSIC)

  • Atul Bansode

    (Institute of Chemical Research of Catalonia (ICIQ))

  • Atsushi Urakawa

    (Institute of Chemical Research of Catalonia (ICIQ))

  • Inma Peral

    (ALBA Light Source, 08290 Cerdanyola del Vallés)

  • Manuel Martínez-Escandell

    (Laboratorio de Materiales Avanzados, Universidad de Alicante)

  • Katsumi Kaneko

    (Research Center for Exotic Nanocarbons, Shinshu University)

  • Francisco Rodríguez-Reinoso

    (Laboratorio de Materiales Avanzados, Universidad de Alicante)

Abstract

Natural methane hydrates are believed to be the largest source of hydrocarbons on Earth. These structures are formed in specific locations such as deep-sea sediments and the permafrost based on demanding conditions of high pressure and low temperature. Here we report that, by taking advantage of the confinement effects on nanopore space, synthetic methane hydrates grow under mild conditions (3.5 MPa and 2 °C), with faster kinetics (within minutes) than nature, fully reversibly and with a nominal stoichiometry that mimics nature. The formation of the hydrate structures in nanospace and their similarity to natural hydrates is confirmed using inelastic neutron scattering experiments and synchrotron X-ray powder diffraction. These findings may be a step towards the application of a smart synthesis of methane hydrates in energy-demanding applications (for example, transportation).

Suggested Citation

  • Mirian E. Casco & Joaquín Silvestre-Albero & Anibal J. Ramírez-Cuesta & Fernando Rey & Jose L. Jordá & Atul Bansode & Atsushi Urakawa & Inma Peral & Manuel Martínez-Escandell & Katsumi Kaneko & Franci, 2015. "Methane hydrate formation in confined nanospace can surpass nature," Nature Communications, Nature, vol. 6(1), pages 1-8, May.
    • Handle: RePEc:nat:natcom:v:6:y:2015:i:1:d:10.1038_ncomms7432
    DOI: 10.1038/ncomms7432
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    Cited by:

    1. Zhang, Shanling & Ma, Yingrui & Xu, Zhenhua & Zhang, Yongtian & Liu, Xiang & Zhong, Xiuping & Tu, Guigang & Chen, Chen, 2024. "Numerical simulation study of natural gas hydrate extraction by depressurization combined with CO2 replacement," Energy, Elsevier, vol. 303(C).
    2. Beckwée, Emile Jules & Houlleberghs, Maarten & Ciocarlan, Radu-George & Chandran, C. Vinod & Radhakrishnan, Sambhu & Hanssens, Lucas & Cool, Pegie & Martens, Johan & Breynaert, Eric & Baron, Gino V. &, 2024. "Structure I methane hydrate confined in C8-grafted SBA-15: A highly efficient storage system enabling ultrafast methane loading and unloading," Applied Energy, Elsevier, vol. 353(PA).
    3. Chen, Shujun & Wang, Di & Wang, Zeyuan & Fu, Yue & Xu, Yiheng & Liu, Dandan, 2023. "Kinetic study of methane storage in hydrophobic ZIF-8 by adsorption-hydration hybrid technology," Energy, Elsevier, vol. 283(C).
    4. Omran, Ahmed & Nesterenko, Nikolay & Valtchev, Valentin, 2022. "Zeolitic ice: A route toward net zero emissions," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    5. Xu, Jiuping & Tang, Min & Liu, Tingting & Fan, Lurong, 2024. "Technological paradigm-based development strategy towards natural gas hydrate technology," Energy, Elsevier, vol. 289(C).
    6. Wang, Pengfei & Teng, Ying & Zhu, Jinlong & Bao, Wancheng & Han, Songbai & Li, Yun & Zhao, Yusheng & Xie, Heping, 2022. "Review on the synergistic effect between metal–organic frameworks and gas hydrates for CH4 storage and CO2 separation applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    7. Zhao, Yang & Qu, Aoxing & Yang, Mingzhao & Dong, Hongsheng & Ge, Yang & Li, Qingping & Liu, Yanzhen & Zhang, Lunxiang & Liu, Yu & Yang, Lei & Song, Yongchen & Zhao, Jiafei, 2024. "Modified balsa wood with natural, flexible porous structure for gas storage," Applied Energy, Elsevier, vol. 353(PA).
    8. Zhang, Zhien & Liu, Zhiming & Pan, Zhen & Baena-Moreno, Francisco M. & Soltanian, Mohamad Reza, 2020. "Effect of porous media and its distribution on methane hydrate formation in the presence of surfactant," Applied Energy, Elsevier, vol. 261(C).
    9. Xie, Yan & Cheng, Liwei & Feng, Jingchun & Zheng, Tao & Zhu, Yujie & Zeng, Xinyang & Sun, Changyu & Chen, Guangjin, 2024. "Kinetics behaviors of CH4 hydrate formation in porous sediments: Non-unidirectional influence of sediment particle size on hydrate formation," Energy, Elsevier, vol. 289(C).
    10. Zhang, Zhengcai & Kusalik, Peter G. & Wu, Nengyou & Liu, Changling & Zhang, Yongchao, 2022. "Molecular simulation study on the stability of methane hydrate confined in slit-shaped pores," Energy, Elsevier, vol. 257(C).

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