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Laser-induced porous graphene films from commercial polymers

Author

Listed:
  • Jian Lin

    (Rice University
    Smalley Institute for Nanoscale Science and Technology, Rice University)

  • Zhiwei Peng

    (Rice University)

  • Yuanyue Liu

    (Rice University)

  • Francisco Ruiz-Zepeda

    (University of Texas at San Antonio, One UTSA Circle)

  • Ruquan Ye

    (Rice University)

  • Errol L. G. Samuel

    (Rice University)

  • Miguel Jose Yacaman

    (University of Texas at San Antonio, One UTSA Circle)

  • Boris I. Yakobson

    (Rice University
    Smalley Institute for Nanoscale Science and Technology, Rice University
    Rice University)

  • James M. Tour

    (Rice University
    Smalley Institute for Nanoscale Science and Technology, Rice University
    Rice University)

Abstract

The cost effective synthesis and patterning of carbon nanomaterials is a challenge in electronic and energy storage devices. Here we report a one-step, scalable approach for producing and patterning porous graphene films with three-dimensional networks from commercial polymer films using a CO2 infrared laser. The sp3-carbon atoms are photothermally converted to sp2-carbon atoms by pulsed laser irradiation. The resulting laser-induced graphene (LIG) exhibits high electrical conductivity. The LIG can be readily patterned to interdigitated electrodes for in-plane microsupercapacitors with specific capacitances of >4 mF cm−2 and power densities of ~9 mW cm−2. Theoretical calculations partially suggest that enhanced capacitance may result from LIG’s unusual ultra-polycrystalline lattice of pentagon-heptagon structures. Combined with the advantage of one-step processing of LIG in air from commercial polymer sheets, which would allow the employment of a roll-to-roll manufacturing process, this technique provides a rapid route to polymer-written electronic and energy storage devices.

Suggested Citation

  • Jian Lin & Zhiwei Peng & Yuanyue Liu & Francisco Ruiz-Zepeda & Ruquan Ye & Errol L. G. Samuel & Miguel Jose Yacaman & Boris I. Yakobson & James M. Tour, 2014. "Laser-induced porous graphene films from commercial polymers," Nature Communications, Nature, vol. 5(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:5:y:2014:i:1:d:10.1038_ncomms6714
    DOI: 10.1038/ncomms6714
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    Cited by:

    1. Khan, Hafsah A. & Tawalbeh, Muhammad & Aljawrneh, Bashar & Abuwatfa, Waad & Al-Othman, Amani & Sadeghifar, Hasan & Olabi, Abdul Ghani, 2024. "A comprehensive review on supercapacitors: Their promise to flexibility, high temperature, materials, design, and challenges," Energy, Elsevier, vol. 295(C).
    2. Viorel Ionescu & Adriana Elena Balan & Alexandra Maria Isabel Trefilov & Ioan Stamatin, 2021. "Exergetic Performance of a PEM Fuel Cell with Laser-Induced Graphene as the Microporous Layer," Energies, MDPI, vol. 14(19), pages 1-18, September.
    3. Jung Bae Lee & Jina Jang & Haoyu Zhou & Yoonjae Lee & Jung Bin In, 2020. "Densified Laser-Induced Graphene for Flexible Microsupercapacitors," Energies, MDPI, vol. 13(24), pages 1-9, December.
    4. Kumar, Rajesh & Singh, Rajesh Kumar & Singh, Dinesh Pratap, 2016. "Natural and waste hydrocarbon precursors for the synthesis of carbon based nanomaterials: Graphene and CNTs," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 976-1006.
    5. Kumar, Rajesh & Joanni, Ednan & Savu, Raluca & Pereira, Matheus S. & Singh, Rajesh K. & Constantino, Carlos J.L. & Kubota, Lauro T. & Matsuda, Atsunori & Moshkalev, Stanislav A., 2019. "Fabrication and electrochemical evaluation of micro-supercapacitors prepared by direct laser writing on free-standing graphite oxide paper," Energy, Elsevier, vol. 179(C), pages 676-684.
    6. Hyeonwoo Kim & Suwon Hwang & Taeseung Hwang & Jung Bin In & Junyeob Yeo, 2021. "Digitally Patterned Mesoporous Carbon Nanostructures of Colorless Polyimide for Transparent and Flexible Micro-Supercapacitor," Energies, MDPI, vol. 14(9), pages 1-11, April.

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