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Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates

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  • Pablo Docampo

    (Clarendon Laboratory, University of Oxford)

  • James M. Ball

    (Clarendon Laboratory, University of Oxford)

  • Mariam Darwich

    (Clarendon Laboratory, University of Oxford)

  • Giles E. Eperon

    (Clarendon Laboratory, University of Oxford)

  • Henry J. Snaith

    (Clarendon Laboratory, University of Oxford)

Abstract

Organometal trihalide perovskite solar cells offer the promise of a low-cost easily manufacturable solar technology, compatible with large-scale low-temperature solution processing. Within 1 year of development, solar-to-electric power-conversion efficiencies have risen to over 15%, and further imminent improvements are expected. Here we show that this technology can be successfully made compatible with electron acceptor and donor materials generally used in organic photovoltaics. We demonstrate that a single thin film of the low-temperature solution-processed organometal trihalide perovskite absorber CH3NH3PbI3-xClx, sandwiched between organic contacts can exhibit devices with power-conversion efficiency of up to 10% on glass substrates and over 6% on flexible polymer substrates. This work represents an important step forward, as it removes most barriers to adoption of the perovskite technology by the organic photovoltaic community, and can thus utilize the extensive existing knowledge of hybrid interfaces for further device improvements and flexible processing platforms.

Suggested Citation

  • Pablo Docampo & James M. Ball & Mariam Darwich & Giles E. Eperon & Henry J. Snaith, 2013. "Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates," Nature Communications, Nature, vol. 4(1), pages 1-6, December.
  • Handle: RePEc:nat:natcom:v:4:y:2013:i:1:d:10.1038_ncomms3761
    DOI: 10.1038/ncomms3761
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    Cited by:

    1. Zhang, Lei & Chen, Zhiqiao & Su, Jing & Li, Jingfa, 2019. "Data mining new energy materials from structure databases," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 554-567.
    2. Yurou Zhang & Miaoqiang Lyu & Tengfei Qiu & Ekyu Han & Il Ku Kim & Min-Cherl Jung & Yun Hau Ng & Jung-Ho Yun & Lianzhou Wang, 2020. "Halide Perovskite Single Crystals: Optoelectronic Applications and Strategical Approaches," Energies, MDPI, vol. 13(16), pages 1-27, August.
    3. Ibn-Mohammed, T. & Koh, S.C.L. & Reaney, I.M. & Acquaye, A. & Schileo, G. & Mustapha, K.B. & Greenough, R., 2017. "Perovskite solar cells: An integrated hybrid lifecycle assessment and review in comparison with other photovoltaic technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 1321-1344.
    4. Ming-Hsien Li & Jun-Ho Yum & Soo-Jin Moon & Peter Chen, 2016. "Inorganic p-Type Semiconductors: Their Applications and Progress in Dye-Sensitized Solar Cells and Perovskite Solar Cells," Energies, MDPI, vol. 9(5), pages 1-28, April.
    5. Cao, Weiran & Li, Zhifeng & Yang, Yixing & Zheng, Ying & Yu, Weijie & Afzal, Rimza & Xue, Jiangeng, 2014. "“Solar tree”: Exploring new form factors of organic solar cells," Renewable Energy, Elsevier, vol. 72(C), pages 134-139.
    6. Chee, A. Kuan-Way, 2023. "On current technology for light absorber materials used in highly efficient industrial solar cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 173(C).
    7. Habibi, Mehran & Zabihi, Fatemeh & Ahmadian-Yazdi, Mohammad Reza & Eslamian, Morteza, 2016. "Progress in emerging solution-processed thin film solar cells – Part II: Perovskite solar cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 1012-1031.
    8. Mesquita, Isabel & Andrade, Luísa & Mendes, Adélio, 2018. "Perovskite solar cells: Materials, configurations and stability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2471-2489.
    9. Joseph Asare & Dahiru M. Sanni & Benjamin Agyei-Tuffour & Ernest Agede & Oluwaseun Kehinde Oyewole & Aditya S. Yerramilli & Nutifafa Y. Doumon, 2021. "A Hybrid Hole Transport Layer for Perovskite-Based Solar Cells," Energies, MDPI, vol. 14(7), pages 1-13, April.

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