Author
Listed:
- Changzheng Wu
(Hefei National Laboratory of Physical Sciences at the Microscale, University of Science and Technology of China)
- Xiuli Lu
(Hefei National Laboratory of Physical Sciences at the Microscale, University of Science and Technology of China)
- Lele Peng
(The University of Texas at Austin)
- Kun Xu
(Hefei National Laboratory of Physical Sciences at the Microscale, University of Science and Technology of China)
- Xu Peng
(Hefei National Laboratory of Physical Sciences at the Microscale, University of Science and Technology of China)
- Jianliu Huang
(Hefei National Laboratory of Physical Sciences at the Microscale, University of Science and Technology of China)
- Guihua Yu
(The University of Texas at Austin)
- Yi Xie
(Hefei National Laboratory of Physical Sciences at the Microscale, University of Science and Technology of China)
Abstract
Two-dimensional materials have been an ideal material platform for constructing flexible ultrathin-film supercapacitors, offering great advantages of flexibility, ultra-thinness and even transparency. Exploring new two-dimensional pseudocapacitive materials with high electrochemical activity is needed to achieve flexible ultrathin-film supercapacitors with higher energy densities. Here we report an inorganic graphene analogue, α1-vanadyl phosphate ultrathin nanosheets with less than six atomic layers, as a promising material to construct a flexible ultrathin-film pseudocapacitor in all-solid-state. The material exhibits a high potential plateau of ~ 1.0 V in aqueous solutions, approaching the electrochemical potential window of water (1.23 V). The as-established flexible supercapacitor achieves a high redox potential (1.0 V) and a high areal capacitance of 8,360.5 μF cm−2, leading to a high energy density of 1.7 mWh cm−2 and a power density of 5.2 mW cm−2.
Suggested Citation
Changzheng Wu & Xiuli Lu & Lele Peng & Kun Xu & Xu Peng & Jianliu Huang & Guihua Yu & Yi Xie, 2013.
"Two-dimensional vanadyl phosphate ultrathin nanosheets for high energy density and flexible pseudocapacitors,"
Nature Communications, Nature, vol. 4(1), pages 1-7, December.
Handle:
RePEc:nat:natcom:v:4:y:2013:i:1:d:10.1038_ncomms3431
DOI: 10.1038/ncomms3431
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Citations
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Cited by:
- Yang, WeiWei & Liu, JianGuo & Zhang, Xiang & Chen, Liang & Zhou, Yong & Zou, ZhiGang, 2017.
"Ultrathin LiFePO4 nanosheets self-assembled with reduced graphene oxide applied in high rate lithium ion batteries for energy storage,"
Applied Energy, Elsevier, vol. 195(C), pages 1079-1085.
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