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Optimal CO2 intake in metastable water film in mesoporous materials

Author

Listed:
  • Gen Li

    (The Hong Kong Polytechnic University)

  • Yong Tao

    (The Hong Kong Polytechnic University)

  • Xinping Zhu

    (CNRS and Université of Montpellier)

  • Yining Gao

    (The Hong Kong Polytechnic University)

  • Peiliang Shen

    (The Hong Kong Polytechnic University)

  • Binbin Yin

    (The Hong Kong Polytechnic University)

  • Romain Dupuis

    (CNRS and Université of Montpellier)

  • Katerina Ioannidou

    (CNRS and Université of Montpellier)

  • Roland J.-M. Pellenq

    (CNRS and Université of Montpellier)

  • Chi Sun Poon

    (The Hong Kong Polytechnic University)

Abstract

The feasibility of carbon mineralization relies on the carbonation efficiency of CO2-reactive minerals, which is largely governed by the water content and state within material mesopores. Yet, the pivotal role of confined water in regulating carbonation efficiency at the nanoscale is not well understood. Here, we show that the maximum CO2 intake occurs at an optimal relative humidity (RHopt) when capillary condensation initiates within the hydrophilic mesopores. At this transition state, the pore becomes filled with metastable low-density water, providing an ideal docking site for CO2 adsorption and forming a mixed metastable state of water/CO2. We prove that RHopt depends on the mesopore size through a Kelvin-like relationship, which yields a robust engineering model to predict RHopt for realistic mineral carbonation. Building upon classical theories of phase transition in hydrophilic mesopores, this study unveils the capacity of the metastable water in CO2 intake and enhances the high-efficiency carbon mineralization with natural ore and industrial wastes in real-world applications.

Suggested Citation

  • Gen Li & Yong Tao & Xinping Zhu & Yining Gao & Peiliang Shen & Binbin Yin & Romain Dupuis & Katerina Ioannidou & Roland J.-M. Pellenq & Chi Sun Poon, 2024. "Optimal CO2 intake in metastable water film in mesoporous materials," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-55125-w
    DOI: 10.1038/s41467-024-55125-w
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    References listed on IDEAS

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    1. Shu-Yuan Pan & Yi-Hung Chen & Liang-Shih Fan & Hyunook Kim & Xiang Gao & Tung-Chai Ling & Pen-Chi Chiang & Si-Lu Pei & Guowei Gu, 2020. "CO2 mineralization and utilization by alkaline solid wastes for potential carbon reduction," Nature Sustainability, Nature, vol. 3(5), pages 399-405, May.
    2. Gert Jan Kramer & Martin Haigh, 2009. "No quick switch to low-carbon energy," Nature, Nature, vol. 462(7273), pages 568-569, December.
    3. Sam Fankhauser & Stephen M. Smith & Myles Allen & Kaya Axelsson & Thomas Hale & Cameron Hepburn & J. Michael Kendall & Radhika Khosla & Javier Lezaun & Eli Mitchell-Larson & Michael Obersteiner & Lava, 2022. "The meaning of net zero and how to get it right," Nature Climate Change, Nature, vol. 12(1), pages 15-21, January.
    4. Phil Renforth, 2019. "The negative emission potential of alkaline materials," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
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