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Breaking the capacity bottleneck of lithium-oxygen batteries through reconceptualizing transport and nucleation kinetics

Author

Listed:
  • Zhuojun Zhang

    (University of Science and Technology of China (USTC))

  • Xu Xiao

    (University of Science and Technology of China (USTC))

  • Aijing Yan

    (University of Science and Technology of China (USTC))

  • Kai Sun

    (University of Science and Technology of China (USTC))

  • Jianwen Yu

    (University of Science and Technology of China (USTC))

  • Peng Tan

    (University of Science and Technology of China (USTC)
    University of Science and Technology of China (USTC))

Abstract

The practical capacity of lithium-oxygen batteries falls short of their ultra-high theoretical value. Unfortunately, the fundamental understanding and enhanced design remain lacking, as the issue is complicated by the coupling processes between Li2O2 nucleation, growth, and multi-species transport. Herein, we redefine the relationship between the microscale Li2O2 behaviors and the macroscopic electrochemical performance, emphasizing the importance of the inherent modulating ability of Li+ ions through a synergy of visualization techniques and cross-scale quantification. We find that Li2O2 particle distributed against the oxygen gradient signifies a compatibility match for the nucleation and transport kinetics, thus enabling the output of the electrode’s maximum capacity and providing a basis for evaluating operating protocols for future applications. In this case, a 150% capacity enhancement is further achieved through the development of a universalizing methodology. This work opens the door for the rules and control of energy conversion in metal-air batteries, greatly accelerating their path to commercialization.

Suggested Citation

  • Zhuojun Zhang & Xu Xiao & Aijing Yan & Kai Sun & Jianwen Yu & Peng Tan, 2024. "Breaking the capacity bottleneck of lithium-oxygen batteries through reconceptualizing transport and nucleation kinetics," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-54366-z
    DOI: 10.1038/s41467-024-54366-z
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    References listed on IDEAS

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