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Utilizing full-spectrum sunlight for ammonia decomposition to hydrogen over GaN nanowires-supported Ru nanoparticles on silicon

Author

Listed:
  • Jinglin Li

    (Shanghai Jiao Tong University)

  • Bowen Sheng

    (Peking University)

  • Yiqing Chen

    (McGill University)

  • Jiajia Yang

    (Peking University)

  • Ping Wang

    (Peking University)

  • Yixin Li

    (Shanghai Jiao Tong University)

  • Tianqi Yu

    (Shanghai Jiao Tong University)

  • Hu Pan

    (Shanghai Jiao Tong University)

  • Liang Qiu

    (Shanghai Jiao Tong University)

  • Ying Li

    (Shanghai Jiao Tong University)

  • Jun Song

    (McGill University)

  • Lei Zhu

    (Shanghai Jiao Tong University)

  • Xinqiang Wang

    (Peking University
    Peking University Yangtze Delta Institute of Optoelectronics
    Peking University)

  • Zhen Huang

    (Shanghai Jiao Tong University)

  • Baowen Zhou

    (Shanghai Jiao Tong University)

Abstract

Photo-thermal-coupling ammonia decomposition presents a promising strategy for utilizing the full-spectrum to address the H2 storage and transportation issues. Herein, we exhibit a photo-thermal-catalytic architecture by assembling gallium nitride nanowires-supported ruthenium nanoparticles on a silicon for extracting hydrogen from ammonia aqueous solution in a batch reactor with only sunlight input. The photoexcited charge carriers make a predomination contribution on H2 activity with the assistance of the photothermal effect. Upon concentrated light illumination, the architecture significantly reduces the activation energy barrier from 1.08 to 0.22 eV. As a result, a high turnover number of 3,400,750 is reported during 400 h of continuous light illumination, and the H2 activity per hour is nearly 1000 times higher than that under the pure thermo-catalytic conditions. The reaction mechanism is extensively studied by coordinating experiments, spectroscopic characterizations, and density functional theory calculation. Outdoor tests validate the viability of such a multifunctional architecture for ammonia decomposition toward H2 under natural sunlight.

Suggested Citation

  • Jinglin Li & Bowen Sheng & Yiqing Chen & Jiajia Yang & Ping Wang & Yixin Li & Tianqi Yu & Hu Pan & Liang Qiu & Ying Li & Jun Song & Lei Zhu & Xinqiang Wang & Zhen Huang & Baowen Zhou, 2024. "Utilizing full-spectrum sunlight for ammonia decomposition to hydrogen over GaN nanowires-supported Ru nanoparticles on silicon," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51810-y
    DOI: 10.1038/s41467-024-51810-y
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    References listed on IDEAS

    as
    1. Kanaan, Riham & Affonso Nóbrega, Pedro Henrique & Achard, Patrick & Beauger, Christian, 2023. "Economical assessment comparison for hydrogen reconversion from ammonia using thermal decomposition and electrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 188(C).
    2. Sun, Shangcong & Jiang, Qiuqiao & Zhao, Dongyue & Cao, Tiantian & Sha, Hao & Zhang, Chuankun & Song, Haitao & Da, Zhijian, 2022. "Ammonia as hydrogen carrier: Advances in ammonia decomposition catalysts for promising hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 169(C).
    3. Huihuang Fang & Simson Wu & Tugce Ayvali & Jianwei Zheng & Joshua Fellowes & Ping-Luen Ho & Kwan Chee Leung & Alexander Large & Georg Held & Ryuichi Kato & Kazu Suenaga & Yves Ira A. Reyes & Ho Viet T, 2023. "Dispersed surface Ru ensembles on MgO(111) for catalytic ammonia decomposition," Nature Communications, Nature, vol. 14(1), pages 1-15, December.
    4. Riham Kanaan & Pedro Henrique Affonso Nóbrega & Patrick Achard & Christian Beauger, 2023. "Economical assessment comparison for hydrogen reconversion from ammonia using thermal decomposition and electrolysis," Post-Print hal-04337525, HAL.
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