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Surface chemical polishing and passivation minimize non-radiative recombination for all-perovskite tandem solar cells

Author

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  • Yongyan Pan

    (Huazhong University of Science and Technology
    Optics Valley Laboratory)

  • Jianan Wang

    (Huazhong University of Science and Technology
    Optics Valley Laboratory)

  • Zhenxing Sun

    (Huazhong University of Science and Technology)

  • Jiaqi Zhang

    (Huazhong University of Science and Technology)

  • Zheng Zhou

    (Huazhong University of Science and Technology)

  • Chenyang Shi

    (Huazhong University of Science and Technology)

  • Sanwan Liu

    (Huazhong University of Science and Technology)

  • Fumeng Ren

    (Huazhong University of Science and Technology)

  • Rui Chen

    (Huazhong University of Science and Technology)

  • Yong Cai

    (Huazhong University of Science and Technology)

  • Huande Sun

    (Huazhong University of Science and Technology)

  • Bin Liu

    (Wuhan University of Technology)

  • Zhongyong Zhang

    (Wuhan University of Technology)

  • Zhengjing Zhao

    (Huaneng Clean Energy Research Institute)

  • Zihe Cai

    (Huaneng Clean Energy Research Institute)

  • Xiaojun Qin

    (Huaneng Clean Energy Research Institute)

  • Zhiguo Zhao

    (Huaneng Clean Energy Research Institute)

  • Yitong Ji

    (Wuhan University of Technology
    Wuhan University of Technology Xiangyang Demonstration Zone)

  • Neng Li

    (Wuhan University of Technology)

  • Wenchao Huang

    (Wuhan University of Technology
    Wuhan University of Technology Xiangyang Demonstration Zone)

  • Zonghao Liu

    (Huazhong University of Science and Technology
    Optics Valley Laboratory)

  • Wei Chen

    (Huazhong University of Science and Technology
    Optics Valley Laboratory)

Abstract

All-perovskite tandem solar cells have shown great promise in breaking the Shockley–Queisser limit of single-junction solar cells. However, the efficiency improvement of all-perovskite tandem solar cells is largely hindered by the surface defects induced non-radiative recombination loss in Sn–Pb mixed narrow bandgap perovskite films. Here, we report a surface reconstruction strategy utilizing a surface polishing agent, 1,4-butanediamine, together with a surface passivator, ethylenediammonium diiodide, to eliminate Sn-related defects and passivate organic cation and halide vacancy defects on the surface of Sn–Pb mixed perovskite films. Our strategy not only delivers high-quality Sn–Pb mixed perovskite films with a close-to-ideal stoichiometric ratio surface but also minimizes the non-radiative energy loss at the perovskite/electron transport layer interface. As a result, our Sn–Pb mixed perovskite solar cells with bandgaps of 1.32 and 1.25 eV realize power conversion efficiencies of 22.65% and 23.32%, respectively. Additionally, we further obtain a certified power conversion efficiency of 28.49% of two-junction all-perovskite tandem solar cells.

Suggested Citation

  • Yongyan Pan & Jianan Wang & Zhenxing Sun & Jiaqi Zhang & Zheng Zhou & Chenyang Shi & Sanwan Liu & Fumeng Ren & Rui Chen & Yong Cai & Huande Sun & Bin Liu & Zhongyong Zhang & Zhengjing Zhao & Zihe Cai , 2024. "Surface chemical polishing and passivation minimize non-radiative recombination for all-perovskite tandem solar cells," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51703-0
    DOI: 10.1038/s41467-024-51703-0
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