IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-51033-1.html
   My bibliography  Save this article

Iodine-induced self-depassivation strategy to improve reversible kinetics in Na-Cl2 battery

Author

Listed:
  • Wenting Feng

    (China University of Petroleum (East China))

  • Xinru Wei

    (China University of Petroleum (East China))

  • Jianhang Yang

    (China University of Petroleum (East China))

  • Chenyu Ma

    (China University of Petroleum (East China))

  • Yiming Sun

    (China University of Petroleum (East China))

  • Junwei Han

    (China University of Petroleum (East China)
    China University of Petroleum (East China))

  • Debin Kong

    (China University of Petroleum (East China))

  • Linjie Zhi

    (China University of Petroleum (East China)
    China University of Petroleum (East China)
    China University of Petroleum (East China))

Abstract

Rechargeable sodium-chlorine (Na-Cl2) batteries show high theoretical specific energy density and excellent adaptability for extreme environmental applications. However, the reported cycle life is mostly less than 500 cycles, and the understanding of battery failure mechanisms is quite limited. In this work, we demonstrate that the substantially increased voltage polarization plays a critical role in the battery failure. Typically, the passivation on the porous cathode caused by the deposition of insulated sodium chloride (NaCl) is a crucial factor, significantly influencing the three-phase chlorine (NaCl/Na+, Cl-/Cl2) conversion kinetics. Here, a self-depassivation strategy enabled by iodine anion (I-)-tuned NaCl deposition was implemented to enhance the chlorine reversibility. The nucleation and growth of NaCl crystals are well balanced through strong coordination of the NaI deposition-dissolution process, achieving depassivation on the cathode and improving the reoxidation efficiency of solid NaCl. Consequently, the resultant Na-Cl2 battery delivers a super-long cycle life up to 2000 cycles.

Suggested Citation

  • Wenting Feng & Xinru Wei & Jianhang Yang & Chenyu Ma & Yiming Sun & Junwei Han & Debin Kong & Linjie Zhi, 2024. "Iodine-induced self-depassivation strategy to improve reversible kinetics in Na-Cl2 battery," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51033-1
    DOI: 10.1038/s41467-024-51033-1
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-51033-1
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-51033-1?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Yu-Chuan Chien & Haidong Liu & Ashok S. Menon & William R. Brant & Daniel Brandell & Matthew J. Lacey, 2023. "Rapid determination of solid-state diffusion coefficients in Li-based batteries via intermittent current interruption method," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    2. Jiarui Yang & Wen-Hao Li & Hai-Tao Tang & Ying-Ming Pan & Dingsheng Wang & Yadong Li, 2023. "CO2-mediated organocatalytic chlorine evolution under industrial conditions," Nature, Nature, vol. 617(7961), pages 519-523, May.
    3. Ya-Nan Yang & Ying-Xiang Li & Yi-Qiu Li & Tao Zhang, 2020. "On-surface lithium donor reaction enables decarbonated lithium garnets and compatible interfaces within cathodes," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    4. Doron Aurbach & Bryan D. McCloskey & Linda F. Nazar & Peter G. Bruce, 2016. "Advances in understanding mechanisms underpinning lithium–air batteries," Nature Energy, Nature, vol. 1(9), pages 1-11, September.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Qiuchen Xu & Shanshan Tang & Nachuan Li & Yan Wang & Xiaoju Zhao & Xiao Zhang & Shitao Geng & Bin Yuan & Shuo Wang & Zhaofeng Ouyang & Meng Liao & Linlin Ma & Ming Shang & Yifan Sun & Huisheng Peng & , 2025. "Harnessing organic electrolyte for non-corrosive and wide-temperature Na-Cl2 battery," Nature Communications, Nature, vol. 16(1), pages 1-13, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Yuanhui & Hao, Liang & Bai, Minli, 2022. "Modeling the multi-step discharge and charge reaction mechanisms of non-aqueous Li-O2 batteries," Applied Energy, Elsevier, vol. 317(C).
    2. Di Prima, Piera & Dessantis, Davide & Versaci, Daniele & Amici, Julia & Bodoardo, Silvia & Santarelli, Massimo, 2025. "Understanding calendar aging degradation in cylindrical lithium-ion cell: A novel pseudo-4-dimensional electrochemical-thermal model," Applied Energy, Elsevier, vol. 377(PC).
    3. Pitchai Ragupathy & Santoshkumar Dattatray Bhat & Nallathamby Kalaiselvi, 2023. "Electrochemical energy storage and conversion: An overview," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 12(2), March.
    4. Anatoly Antipov & Roman Pichugov & Lilia Abunaeva & Shengfu Tong & Mikhail Petrov & Alla Pustovalova & Ivan Speshilov & Natalia Kartashova & Pavel Loktionov & Alexander Modestov & Artem Glazkov, 2022. "Halogen Hybrid Flow Batteries Advances for Stationary Chemical Power Sources Technologies," Energies, MDPI, vol. 15(19), pages 1-20, October.
    5. Deqing Cao & Chuan Tan & Yuhui Chen, 2022. "Oxidative decomposition mechanisms of lithium carbonate on carbon substrates in lithium battery chemistries," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    6. Wang, Yuanhui & Hao, Liang & Bai, Minli, 2023. "Modeling the influence of water on the performance of non-aqueous Li-O2 batteries," Applied Energy, Elsevier, vol. 330(PB).
    7. Hongzhen Liu & Xianglin Ji & Zihao Guo & Xi Wei & Jinchen Fan & Peng Shi & Xiong Pu & Feng Gong & Lizhi Xu, 2024. "A high-current hydrogel generator with engineered mechanoionic asymmetry," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    8. Bo Wu & Ruihu Lu & Chao Wu & Tenghui Yuan & Bin Liu & Xi Wang & Chenyi Fang & Ziyu Mi & Surani Dolmanan & Weng Weei Tjiu & Mingsheng Zhang & Bingqing Wang & Zainul Aabdin & Sui Zhang & Yi Hou & Bote Z, 2025. "Pt/IrOx enables selective electrochemical C-H chlorination at high current," Nature Communications, Nature, vol. 16(1), pages 1-15, December.
    9. Park, Young Je & Choi, Won Young & Choi, Hyunguk & Choi, Seo Won & Park, Jae-ll & Nam, Jieun & Lee, Jong Min & Myung, Kwang Shik & Yoon, Young Gi & Jung, Chi-Young, 2025. "Deciphering the microstructural complexities of compacted carbon fiber paper through AI-enabled digital twin technology," Applied Energy, Elsevier, vol. 377(PD).
    10. Wenpeng Ni & Houjun Chen & Naizhuo Tang & Ting Hu & Wei Zhang & Yan Zhang & Shiguo Zhang, 2024. "High-purity ethylene production via indirect carbon dioxide electrochemical reduction," Nature Communications, Nature, vol. 15(1), pages 1-12, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51033-1. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.